160474

2-Bromothiazole

98%

• Empirical Formula (Hill Notation): C₃H₂BrNS
• CAS Number: 3034-53-5
• Molecular Weight: 164.02
• UNSPSC Code: 12352100
• NACRES: NA.22
• PubChem Substance ID: 24849873
• EC Number: 221-229-4
• Beilstein/REAXYS Number: 105724
• MDL number: MFCD00005316
• Assay: 98%
• Form: liquid

Properties

• Quality Segment: 100
• assay: 98%
• form: liquid
• refractive index: n20/D 1.593 (lit.)
• bp: 171 °C (lit.)
• density: 1.82 g/mL at 25 °C (lit.)
• functional group: bromo
• storage temp.: 2-8°C
• SMILES string: Brc1nccs1
• InChI: 1S/C3H2BrNS/c4-3-5-1-2-6-3/h1-2H
• InChI key: RXNZFHIEDZEUQM-UHFFFAOYSA-N

Description

Application

2-Bromothiazole was used to N-arylate 5- and 7-azaindoles. 2-Bromothiazole was also used as starting reagent in the synthesis of:

• 2-cyanothiazole via cpper-catalyzed cyanation
• 2,4,5-trisubstituted thiazoles
• novel electron-deficient fused pyrrolo[3,2-d:4,5-d′]bisthiazole
• 3-(2′-thiazoyl)indoles

Safety Information

• Storage Class: 12 - Non Combustible Liquids
• WGK: WGK 3
• Flash Point (°F): closed cup - does not flash
• Flash Point (°C): closed cup - does not flash
• PPE (personal protective equipment): Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)