160504

Sigma-Aldrich

9-Fluorenemethanol

99%

Synonym(s):
9-Fluorenylmethanol, 9-(Hydroxymethyl)fluorene
Empirical Formula (Hill Notation):
C14H12O
CAS Number:
Molecular Weight:
196.24
Beilstein/REAXYS Number:
2330017
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

99%

mp

105-107 °C (lit.)

solubility

methanol: soluble 50 mg/mL, clear to hazy, colorless to yellow

SMILES string

OCC1c2ccccc2-c3ccccc13

InChI

1S/C14H12O/c15-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14-15H,9H2

InChI key

XXSCONYSQQLHTH-UHFFFAOYSA-N

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General description

Vibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH and 9-fluorenemethanol-C3H7OH has been studied by IR-UV double-resonance method. Electropolymerization of 9-fluorenemethanol in boron trifluoride diethyl etherate leads to low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) (PFMO) film.

Application

9-Fluorenemethanol, N-protecting reagent, was used in the peptide syntheses. 9-Fluorenemethanol was also used in the synthesis of deoxynucleoside 9-fluorenemethyl phosphorodithioates.

Packaging

10, 50 g in glass bottle

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

The Journal of Organic Chemistry, 57, 6421-6421 (1992)
Low-potential electrosynthesis of novel electroactive poly (9-fluorenemethanol) and its electrochromic and blue-light-emitting properties.
Zhang S, et al.
Electrochimica Acta, 90, 452-460 (2013)
Synthesis, 119-119 (1990)
Journal of the American Chemical Society, 115, 4497-4497 (1993)
2'-Deoxynucleoside Dithiophosphates: Synthesis and Biological Studies1.
Seeberger PH, et al.
Journal of the American Chemical Society, 117(5), 1472-1478 (1995)

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