163015

Sigma-Aldrich

Thallium(III) nitrate trihydrate

Synonym(s):
Thallium trinitrate, TTN
Linear Formula:
Tl(NO3)3 · 3H2O
CAS Number:
Molecular Weight:
444.44
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

reaction suitability

core: thallium
reagent type: catalyst

mp

102-105 °C (lit.)

SMILES string

O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3

InChI key

ZCPIKMRXMBJLCP-UHFFFAOYSA-N

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Related Categories

Application

Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds, for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement, for the selective hydrolysis of thioacetals to carbonyl compounds and for a general synthetic method to 19-norsteroids. Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.

Packaging

25, 100 g in glass bottle

Signal Word

Danger

Hazard Codes

T+,N

Risk Statement

26/28-33-51/53

Safety Statement

13-28-45-61

RIDADR

UN 2727 5.1(6.1) / PGII

WGK Germany

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Enrico Bugiardini et al.
Frontiers in neurology, 9, 456-456 (2018-07-13)
Objective: Distal myopathies are a diagnostically challenging group of diseases. We wanted to understand the value of MRI in the current clinical setting and explore the potential for optimizing its clinical application. Methods: We retrospectively audited the diagnostic workup in...
Kevin Yauy et al.
The Journal of molecular diagnostics : JMD, 20(4), 465-473 (2018-04-25)
Interpretation of next-generation sequencing constitutes the main limitation of molecular diagnostics. In diagnosing myopathies and muscular dystrophies, another issue is efficiency in predicting the pathogenicity of variants identified in large genes, especially TTN; current in silico prediction tools show limitations...
Synthetic Communications, 9, 301-301 (1979)
Journal of the American Chemical Society, 98, 3037-3037 (1976)
Journal of the Chemical Society. Chemical Communications, 1026-1026 (1990)
Articles
Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis
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