Hydroxymethanesulfinic acid monosodium salt dihydrate

Name: Hydroxymethanesulfinic acid monosodium salt dihydrate
Brand: ALDRICH
Price: 40.2 USD

Synonym(s):

Sodium formaldehydesulfoxylate

Slide 1 of 3

Select a Size

100 G

$40.20

1 KG

$97.80

$40.20

Check Cart for Availability

One Time Order

Request a Bulk Order

Subscriptions are currently unavailable.

About This Item

Linear Formula:

HOCH₂SO₂Na · 2H₂O

CAS Number:

6035-47-8

Molecular Weight:

154.12

NACRES:

NA.22

PubChem Substance ID:

24849753

UNSPSC Code:

12352100

EC Number:

205-739-4

MDL number:

MFCD00150598

Key Documents

View All Documentation

InChI key

UCWBKJOCRGQBNW-UHFFFAOYSA-M

InChI

1S/CH4O3S.Na.2H2O/c2-1-5(3)4;;;/h2H,1H2,(H,3,4);;2*1H2/q;+1;;/p-1

SMILES string

[Na+].[H]O[H].[H]O[H].OCS([O-])=O

form

powder

mp

64-68 °C (lit.)

solubility

alcohol: slightly soluble(lit.)
benzene: slightly soluble(lit.)
chloroform: slightly soluble(lit.)
diethyl ether: slightly soluble(lit.)
water: freely soluble(lit.)

functional group

sulfinic acid

Quality Level

100

Related Categories

Organic Building Blocks

Chemical Building Blocks

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item	146617	571024	242837
Sigma-Aldrich 163511 Hydroxymethanesulfinic acid monosodium salt dihydrate	Sigma-Aldrich 146617 Bathophenanthrolinedisulfonic acid disodium salt hydrate	Sigma-Aldrich 571024 Chlorosulfonic acid	Sigma-Aldrich 242837 2-Bromohexanoic acid
solubility alcohol: slightly soluble(lit.), chloroform: slightly soluble(lit.), water: freely soluble(lit.), benzene: slightly soluble(lit.), diethyl ether: slightly soluble(lit.)	solubility water: soluble 100 mg/mL, clear to slightly hazy, yellow (to red)	solubility acetic acid: soluble(lit.), chloroform: soluble(lit.), dichloromethane: soluble(lit.)	solubility alcohol: soluble(lit.), diethyl ether: soluble(lit.)
Quality Level 100	Quality Level 100	Quality Level 200	Quality Level 100
form powder	form powder	form -	form liquid
mp 64-68 °C (lit.)	mp 300 °C	mp -	mp -
functional group sulfinic acid	functional group -	functional group -	functional group bromo, carboxylic acid

General description

Oxidation reation of hydroxymethanesulfinic acid with chlorite has been studied in the pH range 4-8[1]. It is a sulfur-containing reducing agent[2].

pictograms

GHS08

signalword

Warning

hcodes

H341,H361d

pcodes

P201 - P202 - P280 - P308 + P313 - P405 - P501

Hazard Classifications

Muta. 2 - Repr. 2

supp_hazards

EUH032

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Oxyhalogen-Sulfur Chemistry: Oxidation of Hydroxymethanesulfinic Acid by Chlorite 1.

Salem MA, et al.

The Journal of Physical Chemistry, 100(22), 9377-9384 (1996)

Recent trends in the chemistry of sulfur-containing reducing agents.

Makarov, SV.

Russ. Chem. Rev., 70(10), 885-895 (2001)

Reactive oxygen species in the aerobic decomposition of sodium hydroxymethanesulfinate.

S V Makarov et al.

Archives of biochemistry and biophysics, 367(2), 289-296 (1999-07-09)

Sodium hydroxymethanesulfinate, (HOCH2SO2Na, HMS) is relatively stable in aqueous alkaline environments, but rapidly decomposes in acidic medium to give a variety of products that include sulfur dioxide. A detailed kinetic and mechanistic study of the decomposition of HMS in slightly

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service