171441

Sigma-Aldrich

Trifluoroiodomethane

99%

Synonym(s):
Trifluoromethyl iodide, Iodotrifluoromethane, Perfluoromethyl iodide
Empirical Formula (Hill Notation):
CF3I
CAS Number:
Molecular Weight:
195.91
Beilstein/REAXYS Number:
1732740
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

99%

bp

−22.5 °C (lit.)

mp

<−78 °C (lit.)

SMILES string

FC(F)(F)I

InChI

1S/CF3I/c2-1(3,4)5

InChI key

VPAYJEUHKVESSD-UHFFFAOYSA-N

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Packaging

25, 100 g in Sure-Pac™

Application

Reagent used in the rhodium-catalyzed α-trifluoromethylation of α,ß-unsaturated ketones.

Other Notes

In Europe, for 171441-100G-EU packaging: 1000 mL of aluminium cylinder equipped with stainless steel valve.

Recommended products

  • For 171441-25G/100G: Brass hose adapter Z146811 or brass body mini gas regulator Z513539 is recommended.
  • In Europe, for 171441-100G-EU outlet fitting: DIN 477-1 no. 1, Z742162 or Z742164 are the recommended regulators.
  • For 171441-100G and 171441-25G: outlet fitting no 99112 is the recommended outlet fitting.

Signal Word

Warning

Hazard Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 1956 2.2

WGK Germany

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

D E Dodd et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 35(1), 64-77 (1997-01-01)
Trifluoroiodomethane (CF3I) is being considered as a replacement compound for halon fire suppressants. Its structure is similar to that of Halon 1301 (CF3Br), but it has very low ozone depletion potential compared to CF3Br. As part of the process of...
Discovering and verifying elusive fullerene cage isomers: structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C(78)-D3h5)(CF3)12.
Natalia B Shustova et al.
Angewandte Chemie (International ed. in English), 46(22), 4111-4114 (2007-04-25)
Kelvin Anggara et al.
Science advances, 4(10), eaau2821-eaau2821 (2018-10-13)
Collision geometry is central to reaction dynamics. An important variable in collision geometry is the miss-distance between molecules, known as the "impact parameter." This is averaged in gas-phase molecular beam studies. By aligning molecules on a surface prior to electron-induced...
C Stefan Lehmann et al.
Faraday discussions, 153, 173-187 (2011-01-01)
The control of multichannel ionic fragmentation dynamics in CF3I is studied by femtosecond pulse shaping and velocity map photoelectron photoion coincidence imaging. When CF3I is photoexcited with femtosecond laser pulses around 540 nm there are two major ions observed in...
D E Dodd et al.
Inhalation toxicology, 11(11), 1041-1055 (1999-11-24)
CF(3)I is being considered by the U.S. Air Force as a replacement for Halon 1301 for fire-extinguishing requirements in unoccupied spaces. The purpose of this study was to determine and evaluate the potential for CF(3)I to produce reproductive toxicity and...
Articles
In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)
Read More

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