176494

Sigma-Aldrich

Europium tris3-(trifluoromethylhydroxymethylene)-(+)-camphorate

Synonym(s):
Eu(facam)3, Eu(tfc)3, Tris(3-trifluoroacetyl-d-camphorato)europium(III), Europium(III) tris3-(trifluoromethylhydroxymethylene)-d-camphorate, Tris3-(trifluoromethylhydroxymethylene)-d-camphoratoeuropium(III)
Empirical Formula (Hill Notation):
C36H42EuF9O6
CAS Number:
Molecular Weight:
893.66
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

optical activity

α20/D +165°, c = 1% in chloroform (solvent is ethanol free)

application(s)

NMR: suitable

SMILES string

CC1(C)C2CCC1(C)C(=O)\C2=C(/OEu(O\C(=C3\C4CCC(C)(C3=O)C4(C)C)C(F)(F)F)O\C(=C5\C6CCC(C)(C5=O)C6(C)C)C(F)(F)F)C(F)(F)F

InChI

1S/3C12H15F3O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15;/h3*6,17H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7-;

InChI key

BWIHMSGCCRUUCZ-NCJHBDPTSA-K

Application

Reactant involved in:
  • The synthesis of europium acetylcamphorate phosphine oxide complexes
  • Reactions with 1,10-N,N′-phenanthroline dioxide derivatives
Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride.

Packaging

1 g in glass bottle
100 mg in glass bottle

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Analytical Chemistry, 59, 562-562 (1987)

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