Documents
179701
Triethylborane solution
1.0 M in THF
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form
liquid
Quality Level
reaction suitability
reagent type: reductant
concentration
1.0 M in THF
density
0.865 g/mL at 25 °C
SMILES string
CCB(CC)CC
InChI
1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3
InChI key
LALRXNPLTWZJIJ-UHFFFAOYSA-N
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Related Categories
1 of 4
This Item | 257192 | 195030 | 213438 |
|---|---|---|---|
| reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant |
| density 0.865 g/mL at 25 °C | density 0.677 g/mL at 25 °C (lit.) | density 0.675 g/mL at 25 °C | density 0.902 g/mL at 25 °C |
| concentration 1.0 M in THF | concentration - | concentration 1.0 M in hexanes | concentration 1.0 M in THF |
Application
- Allylation of aldehydes
- Decarboxylative C-C bond cleavage reactions
- Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations
- Regioselective hydroxyalkylation of unsaturated oxime ethers
Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes
Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential
- Allylation of aldehydes
- Decarboxylative C-C bond cleavage reactions
- Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations
- Regioselective hydroxyalkylation of unsaturated oxime ethers
It can be employed as a reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes and for the synthesis of tetramethylammonium trialkylphenylborate salts.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1A - Water-react 2
Supplementary Hazards
Storage Class Code
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 1
Flash Point(F)
1.4 °F - closed cup
Flash Point(C)
-17 °C - closed cup
Personal Protective Equipment
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