- 179728
179728
Super-Hydride® solution
1.0 M lithium triethylborohydride in THF
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form
liquid
Quality Level
reaction suitability
reagent type: reductant
concentration
1.0 M lithium triethylborohydride in THF
density
0.892 g/mL at 25 °C
SMILES string
[Li+].[H][B-](CC)(CC)CC
InChI
1S/C6H16B.Li/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1
InChI key
WCJAYABJWDIZAJ-UHFFFAOYSA-N
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This Item | 703508 | 214965 | 214973 |
|---|---|---|---|
| form liquid | form liquid | form liquid | form liquid |
| reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant |
| density 0.892 g/mL at 25 °C | density 0.883 g/mL at 25 °C | density 0.731 g/mL at 25 °C | density 1.23 g/mL at 25 °C |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 200 |
| concentration 1.0 M lithium triethylborohydride in THF | concentration 10 % (w/w), 2.3 M in 2-methyltetrahydrofuran | concentration 1.0 M in heptane | concentration 1.0 M in methylene chloride |
General description
Application
- To reduce alkyl halides to alkanes via dehydrogenation reactions.
- For the selective reduction of epoxides to Markovnikov alcohols.
- To reduce tosylates or mesylates primary alcohols to hydrocarbons.
- For reductive cyclization reactions for the preparation of useful intermediates.
- In the synthesis of hepta(manno-3-deoxy-6-O-t-butyldimethylsilyl)-β-cyclodextrin by reduction of hepta(manno-2,3-anhydro-6-O-t-butyldimethylsilyl)-β-cyclodextrin.
- For hydrodefluorination of C-F bonds using Ni catalyst.
- To prepare alkynyl alcohols from cleavage of cyclic keto-vinyl triflates.
- In the stereoselective reduction of bicyclic imides, isoquinolines, and pyridines.
- To prepare tungsten and molybdenum hydride complexes.
Packaging
Legal Information
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
1.4 °F - closed cup
Flash Point(C)
-17 °C - closed cup
Personal Protective Equipment
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