185841

Sigma-Aldrich

Dicyclohexylamine

99%

Linear Formula:
(C6H11)2NH
CAS Number:
Molecular Weight:
181.32
Beilstein/REAXYS Number:
605923
EC Number:
MDL number:
eCl@ss:
39030438
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

vapor density

6 (vs air)

vapor pressure

12 mmHg ( 37.7 °C)

assay

99%

refractive index

n20/D 1.484 (lit.)

bp

117-120 °C/10 mmHg
256 °C (lit.)

mp

−2 °C (lit.)

solubility

organic solvents: soluble
water: very slightly soluble

density

0.912 g/mL at 20 °C (lit.)

SMILES string

C1CCC(CC1)NC2CCCCC2

InChI

1S/C12H23N/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h11-13H,1-10H2

InChI key

XBPCUCUWBYBCDP-UHFFFAOYSA-N

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Application

Dicyclohexylamine was used to constitute ionic liquid matrices for bacterial analysis in matrix assisted laser desorption/ionisation mass spectrometry. It was used to develop a new palladium catalyst for Suzuki coupling reaction of aryl bromides with boronic acids. It was used as extractant in determination of gold(III) by dispersive liquid-liquid microextraction and electrothermal atomic absorption spectrometry.

Packaging

5, 100, 500 g in glass bottle
2 kg in glass bottle

Signal Word

Danger

Hazard Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 2565 8 / PGIII

WGK Germany

WGK 2

Flash Point(F)

204.8 °F - closed cup

Flash Point(C)

96 °C - closed cup

Shigehiro Kagaya et al.
Talanta, 80(3), 1364-1370 (2009-12-17)
A combined method with dispersive liquid-liquid microextraction (DLLME) and electrothermal atomic absorption spectrometry (ETAAS) has been developed for determining gold(III). Dicyclohexylamine, a new extractant for gold(III), showed excellent performance in DLLME. Acetone was indispensable to the quantitative extraction of gold(III)...
Bin Tao et al.
The Journal of organic chemistry, 69(13), 4330-4335 (2004-06-19)
A new palladium catalyst (DAPCy) made from Pd(OAc)(2) and commercially available, inexpensive dicyclohexylamine has been developed for the Suzuki coupling reaction of aryl bromides with boronic acids to give the coupling products in good to high yields. The air-stable catalyst...
R H Davis et al.
Proceedings of the National Academy of Sciences of the United States of America, 82(12), 4105-4109 (1985-06-01)
We wished to identify metabolic signals governing changes in ornithine decarboxylase (L-ornithine carboxy-lyase, EC 4.1.1.17) activity in Neurospora crassa. By manipulations of the ornithine supply and by the use of inhibitors of the polyamine pathway, we found that spermidine negatively...
A F Tiburcio et al.
Plant cell, tissue and organ culture, 9, 111-120 (1987-01-01)
We studied the effects of inhibitors of ornithine decarboxylase (ODC), arginine decarboxylase (ADC) and spermidine synthase (Spd synthase) on organogenesis and the titers of polyamines (PA) and alkaloids in tobacco calli. DL-alpha-diffluromethylarginine (DFMA) and D-arginine (D-Arg), both inhibitors of ADC...
T Wang et al.
Journal of pharmaceutical and biomedical analysis, 15(5), 593-599 (1997-02-01)
A simple, selective, sensitive, accurate and relatively inexpensive method for the determination of palladium in bulk pharmaceutical chemicals (BPC) and their synthetic intermediates by graphite furnace atomic absorption spectroscopy has been developed and validated. Sample preparation by direct dissolution of...

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