186201
Methyllithium lithium bromide complex solution
1.5 M in diethyl ether
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MeLi·LiBr, Methyllithium complex with lithium bromide, Methyllithium lithium bromide complex (1:1)
CH3Li · LiBr
Recommended Products
form
liquid
Quality Level
concentration
1.5 M in diethyl ether
density
0.852 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li+].[Br-].[Li]C
InChI
1S/CH3.BrH.2Li/h1H3;1H;;/q;;;+1/p-1
InChI key
XLIKYFMMLMHLKL-UHFFFAOYSA-M
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Application
Methyllithium lithium bromide complex solution (MeLi.LiBr) can be used as a methylating agent for the α-methylation of alkoxyaryl ketones.
Packaging
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
wgk_germany
WGK 3
flash_point_f
-18.4 °F
flash_point_c
-28 °C
Certificates of Analysis (COA)
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Unusual alpha-methylation of alkoxyaryl ketones with higher order methyl cuprate and lithium bromide.
The Journal of organic chemistry, 65(26), 9241-9244 (2001-01-10)
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