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186384

Sigma-Aldrich

N,N-Dimethyl-p-phenylenediamine sulfate salt

98%

Synonym(s):
4-(Dimethylamino)aniline sulfate salt, DMPPDA, 4-Amino-N,N-dimethylaniline sulfate salt
Linear Formula:
(CH3)2NC6H4NH2·H2SO4
CAS Number:
Molecular Weight:
234.27
Beilstein:
4612278
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

98%

bp

495 °C (lit.)

mp

200-205 °C (dec.) (lit.)

solubility

water: soluble 50 mg/mL, clear to hazy, colorless to faintly yellow or pink

SMILES string

OS(O)(=O)=O.CN(C)c1ccc(N)cc1

InChI

1S/C8H12N2.H2O4S/c1-10(2)8-5-3-7(9)4-6-8;1-5(2,3)4/h3-6H,9H2,1-2H3;(H2,1,2,3,4)

InChI key

GLUKPDKNLKRLHX-UHFFFAOYSA-N

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Application

N,N-Dimethyl-p-phenylenediamine sulfate salt was used:
  • to investigate the role of H2S in cardioprotection induced by ischemic preconditioning in rat heart
  • in spectrophotometric determination of gold(III) in gold-pharmaceuticals such as sodium aurothimaleate and auranofin
  • to investigate colonic tissue H2S production using the acetate trapping assay system

Packaging

25, 100 g in glass bottle

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK Germany

WGK 3

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

New and sensitive spectrophotometric determination of gold (III) with N, N-dimethyl-p-phenylenediamine and potassium persulfate.
Mori I, et al.
Analytical Letters, 30(5), 953-961 (1997)
Kyle L Flannigan et al.
American journal of physiology. Gastrointestinal and liver physiology, 301(1), G188-G193 (2011-04-09)
Hydrogen sulfide (H(2)S) is an important modulator of many aspects of digestive function, both in health and disease. Colonic tissue H(2)S synthesis increases markedly during injury and inflammation and appears to contribute to resolution. Some of the bacteria residing in...
Jin-Song Bian et al.
The Journal of pharmacology and experimental therapeutics, 316(2), 670-678 (2005-10-06)
Endogenous H(2)S is synthesized mainly by cystathionine gamma-lyase in the heart. The present study investigated the role of H(2)S in cardioprotection induced by ischemic preconditioning. We have examined the effect of endogenous H(2)S and exogenous application of NaHS (H(2)S donor)...
Kraiwan Punyain et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 83(1), 368-378 (2011-09-20)
Organic radical cations form dicationic dimers in solution, observed experimentally as diamagnetic species in temperature-dependent EPR and low temperature UV/Vis spectroscopy. Dimerization of paraphenylenediamine, N,N-dimethyl-paraphenylenediamine and 2,3,5,6-tetramethyl-paraphenylenediamine radical cation in ethanol/diethylether mixture was investigated theoretically according to geometry, energetics and...
Jean-François Lesgards et al.
International journal for vitamin and nutrition research. Internationale Zeitschrift fur Vitamin- und Ernahrungsforschung. Journal international de vitaminologie et de nutrition, 75(1), 11-18 (2005-04-16)
Assessment of the antioxidant activity of vitamins and other compounds is of interest in the understanding of their in vivo effects. In this study, we have investigated the activity of several lipid and water-soluble vitamins in human whole blood. Measurements...

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