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188913

Catecholborane

98%

Synonym(s):

Catecholatoborane, Catecholborane (CB), Pyrocatecholborane

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Size/SKUAvailabilityPrice
25 g

Available to ship TODAYfromMILWAUKEE

$325.00
100 g

Available to ship TODAYfromMILWAUKEE

$663.00

About This Item

Empirical Formula (Hill Notation):
C6H5BO2
CAS Number:
Molecular Weight:
119.91
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-991-5
Beilstein/REAXYS Number:
972072
MDL number:
Assay:
98%
Form:
liquid

$325.00


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Quality Segment

assay

98%

form

liquid

reaction suitability

reagent type: reductant

refractive index

n20/D 1.507 (lit.)

bp

50 °C/50 mmHg (lit.)

mp

12 °C (lit.)

density

1.125 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

[bH]1oc2ccccc2o1

InChI

1S/C6H5BO2/c1-2-4-6-5(3-1)8-7-9-6/h1-4,7H

InChI key

CENMEJUYOOMFFZ-UHFFFAOYSA-N

Application

Used to prepare B-alkylcatecholboranes which were used, in turn, to generate alkyl radicals forming aryl ethers from quinones.[1] Employed in a preparation of C2-symmetric boron complexes from methylenebis(oxazolines) used for enantioselective reduction of ketones.
A monofunctional hydroborating agent which reduces β-hydroxyketones to 1,3-diols. Effects conjugate reduction of α,β-enones.

Other Notes

Material may precipitate naturally over time; the precipitate isinert

Legal Information

Made under U.S. Pat. No. 6,204,405.

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This Item
225762SML3460SML1527
assay

98%

assay

-

assay

≥97% (HPLC)

assay

≥98% (HPLC)

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

-

reaction suitability

-

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-10 to -25°C

storage temp.

−20°C

form

liquid

form

liquid

form

powder

form

powder

refractive index

n20/D 1.507 (lit.)

refractive index

-

refractive index

-

refractive index

-

bp

50 °C/50 mmHg (lit.)

bp

-

bp

-

bp

-


pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

35.6 °F - closed cup

flash_point_c

2 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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