2-Methyl-2-nitropropane

Name: 2-Methyl-2-nitropropane
Brand: ALDRICH
Price: 162 USD

99%

Synonym(s):

1,1-Dimethyl-1-nitroethane, 2-Methyl-2-nitropropane, 2-Nitro-2-methylpropane, 2-Nitroisobutane, Trimethylnitromethane

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25 G

$162.00

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About This Item

Linear Formula:

(CH₃)₃CNO₂

CAS Number:

594-70-7

Molecular Weight:

103.12

NACRES:

NA.22

PubChem Substance ID:

24851362

UNSPSC Code:

12352100

EC Number:

209-851-4

MDL number:

MFCD00007393

Assay:

99%

Key Documents

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InChI key

AIMREYQYBFBEGQ-UHFFFAOYSA-N

InChI

1S/C4H9NO2/c1-4(2,3)5(6)7/h1-3H3

SMILES string

CC(C)(C)[N+]([O-])=O

assay

99%

refractive index

n20/D 1.4 (lit.)

bp

126-127 °C (lit.)

density

0.95 g/mL at 25 °C (lit.)

functional group

amine, nitro

Quality Level

100

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Chemistry & Biochemicals

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1 of 4

This Item	294667	142476	130265
Sigma-Aldrich 189022 2-Methyl-2-nitropropane	Sigma-Aldrich 294667 2-Methyl-2-pentenal	Sigma-Aldrich 142476 2-Butyl-2-ethyl-1,3-propanediol	Sigma-Aldrich 130265 2-Nitropropane
assay 99%	assay 97%	assay 99%	assay ≥96%
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 200
bp 126-127 °C (lit.)	bp 137-138 °C/765 mmHg (lit.)	bp 178 °C/50 mmHg (lit.)	bp 120 °C (lit.)
density 0.95 g/mL at 25 °C (lit.)	density 0.86 g/mL at 25 °C (lit.)	density -	density 0.992 g/mL at 25 °C (lit.)
refractive index n20/D 1.4 (lit.)	refractive index n20/D 1.45 (lit.)	refractive index -	refractive index n20/D 1.394 (lit.)
functional group amine	functional group aldehyde	functional group hydroxyl	functional group amine, nitro

General description

Photodissociation of 2-methyl-2-nitropropane at 193 and 248nm leads to the formation of OH fragment and electronically excited NO₂[1]. Hydrolysis reaction of 2-methyl-2-nitropropane in the presence of platinum-alumina catalyst yields N₂O.

pictograms

GHS02,GHS07

signalword

Danger

hcodes

H225,H315,H319,H335

pcodes

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

66.2 °F - closed cup

flash_point_c

19 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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N₂O formation during organic nitro compounds' hydrolysis on platinum based catalysts.

Joubert E, et al.

Applied Catalysis. B, Environmental, 23(2), L83-L87 (1999)

Photodissociation dynamics of 2-nitropropane and 2-methyl-2-nitropropane at 248 and 193 nm.

Sumana Sengupta et al.

The journal of physical chemistry. A, 112(49), 12572-12581 (2008-12-05)

Dynamics of formation of electronically excited NO2 and formation of OH fragment, during photo dissociation of 2-nitropropane (NP) and 2-methyl-2-nitropropane (MNP), were investigated at 193 and 248 nm. The radiative lifetime of the electronically excited NO2 fragment, observed at 193

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