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MilliporeSigma

194131

Oxalic acid

98%

Oxalic acid

Synonym(s):

Ethanedioic acid

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$53.60

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$53.70

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$196.00

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About This Item

Linear Formula:
HO2CCO2H
CAS Number:
Molecular Weight:
90.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-634-3
Beilstein/REAXYS Number:
385686
MDL number:
Assay:
98%
Form:
powder or crystals

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InChI key

MUBZPKHOEPUJKR-UHFFFAOYSA-N

InChI

1S/C2H2O4/c3-1(4)2(5)6/h(H,3,4)(H,5,6)

SMILES string

OC(=O)C(O)=O

vapor density

4.4 (vs air)

vapor pressure

<0.01 mmHg ( 20 °C)

assay

98%

form

powder or crystals

pH

(1.3 at 9 g/l)

mp

189.5 °C (dec.) (lit.)

solubility

water: soluble 108 g/L at 25 °C

density

1.65 g/cm3 at 18.5 °C

functional group

carboxylic acid

Quality Level

Gene Information

human ... SRC(6714)

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1 of 4

This Item
2411727568823-0890
assay

98%

assay

≥99%

assay

≥99.0% (RT)

assay

≥97.0%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

-

form

powder or crystals

form

powder or crystals

form

crystals

form

crystalline

pH

(1.3 at 9 g/l)

pH

-

pH

-

pH

-

solubility

water: soluble 108 g/L at 25 °C

solubility

water: soluble ~108 g/L at 25 °C

solubility

-

solubility

water: 108 g/L at 25 °C

vapor density

4.4 (vs air)

vapor density

4.4 (vs air)

vapor density

4.4 (vs air)

vapor density

4.4 (vs air)

Application

Oxalic acid was used in determination of oxamic acid, oxalic acid, and oxamide in hydrophobic drug substance matrix by ion-exclusion chromatography[1]. It was used in the synthesis of three-dimensionally ordered macroporous metal oxides or carbonates via templating with polystyrene spheres[2]. It was employed as supporting electrolyte during electrochemical synthesis of polyaniline-polypyrrole composite coatings[3].

General description

Oxalic acid is a dicarboxylic acid used in dehydration, elimination, protection, deprotection, condensation, and decarboxylation reactions.[4]

Oxalic acid is present as a potential impurity in some active pharmaceutical ingredients[1].

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 1

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Characterization of polyaniline-polypyrrole composite coatings on low carbon steel: a XPS and infrared spectroscopy study.
Rajagopalan R and Iroh JO.
Applied Surface Science, 218(1), 58-69 (2003)
Oxalic Acid
Hamilton GS
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
General synthesis of periodic macroporous solids by templated salt precipitation and chemical conversion.
Yan H, et al.
Chemistry of Materials, 12(4), 1134-1141 (2000)
L Yang et al.
Journal of pharmaceutical and biomedical analysis, 22(3), 487-493 (2000-04-15)
Oxalic acid, oxamic acid and oxamide are potential impurities in some active pharmaceutical ingredients (API). The retention and separation of oxalic and oxamic acids are particularly challenging using conventional reversed-phase HPLC due to their high polarity. An ion-exclusion chromatography (IEC)
Xianlai Zeng et al.
Journal of hazardous materials, 295, 112-118 (2015-04-22)
With the booming of consumer electronics (CE) and electric vehicle (EV), a large number of spent lithium-ion battery (LIBs) have been generated worldwide. Resource depletion and environmental concern driven from the sustainable industry of CE and EV have motivated spent

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    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. What temperature should this item be stored and should it be stored away from light?

    1 answer
    1. This product may be stored at room temperature, tightly closed, in a dry place. While the material is not light sensitive, it is hygroscopic.

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  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  1. USA
    • Review 1
    • Vote 1
    3 out of 5 stars.

    material is fine...shipping and overall cost seems exhorbitant

    material is fine...shipping and overall cost seems exhorbitant

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