196223

Sigma-Aldrich

B-Methoxy-9-BBN solution

1.0 M in hexanes

Synonym(s):
9-Methoxy-9-borabicyclo3.3.1nonane
Empirical Formula (Hill Notation):
C9H17BO
CAS Number:
Molecular Weight:
152.04
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

reaction suitability

reaction type: C-C Bond Formation

concentration

1.0 M in hexanes

density

0.716 g/mL at 25 °C

SMILES string

COB1C2CCCC1CCC2

InChI

1S/C9H17BO/c1-11-10-8-4-2-5-9(10)7-3-6-8/h8-9H,2-7H2,1H3/t8-,9+

InChI key

UNGDGQYONLTNJZ-DTORHVGOSA-N

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Related Categories

Application

  • Pro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivatives
  • Catalyst for preparation of linear allenes from other allenes

Reactant for:
  • Stereoconvergent Suzuki cross-coupling reactions
  • B-alkyl Suzuki-Miyaura cross-coupling reactions
  • Preparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanoma
  • Asymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement

Packaging

100 mL in Sure/Seal™

Signal Word

Danger

Target Organs

Central nervous system

Hazard Codes

F,Xn,N

Risk Statement

11-38-48/20-51/53-62-65-67

Safety Statement

36/37-61-62

RIDADR

UN 1993BE 3 / PGII

WGK Germany

WGK 3

Flash Point(F)

-14.8 °F - closed cup

Flash Point(C)

-26 °C - closed cup

Certificate of Analysis
Certificate of Origin

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