19997

Sigma-Aldrich

tert-Butyl hydroperoxide solution

packed in FEP bottles, ~5.5 M in decane (over molecular sieve 4Å)

Synonym(s):
1,1-Dimethylethyl hydroperoxide, TBHP, 2-Hydroperoxy-2-methylpropane
Linear Formula:
(CH3)3COOH
CAS Number:
Molecular Weight:
90.12
Beilstein/REAXYS Number:
1098280
MDL number:
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

Quality Level

assay

52.9-66.8% (iodometric)

form

liquid

quality

packed in FEP bottles

reaction suitability

reagent type: oxidant

concentration

~5.5 M in decane (over molecular sieve 4Å)

refractive index

n20/D 1.403

density

0.83 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

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Application

Used in oxidative desulfurization of fuelsand as an oxidant for the epoxidation of styrene.

Packaging

25, 100 mL in PFA/FEP bottle

Other Notes

Safe and stable oxidant for the Sharpless epoxidation

Signal Word

Danger

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 3105A8 8(5.2)

WGK Germany

WGK 3

Flash Point(F)

109.4 °F - closed cup

Flash Point(C)

43 °C - closed cup

Certificate of Analysis
Certificate of Origin
Controlled synthesis of a- and c-Fe2O3 nanoparticles via thermolysis of PVA gels and studies on a-Fe2O3 catalyzed styrene epoxidation.
Bepari RA,et al.
Journal of Saudi Chemical Society (2014)
Oxidative desulfurization of fuel oil. Part I. Oxidation of dibenzothiphenes using tert-butyl hydroperoxide
Wang D,et al.
Applied Catalysis A: General, 253, 91-99 (2003)
K. Akashi et al.
The Journal of Organic Chemistry, 43, 2063-2063 (1978)
T. Katsuki et al.
Org. React., 48, 1-1 (1996)
Qiong Tang et al.
Ultrasonics sonochemistry, 20(5), 1168-1175 (2013-03-30)
This work investigated the ultrasonic assisted oxidative desulfurization of bunker-C oil with TBHP/MoO3 system. The operational parameters for the desulfurization procedure such as ultrasonic irradiation time, ultrasonic wave amplitude, catalyst initial concentration and oxidation agent initial concentration were studied. The...

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