19999

Sigma-Aldrich

tert-Butyl hydroperoxide solution

packed in FEP bottles, ~5.5 M in nonane (over molecular sieve 4 Å)

Synonym(s):
1,1-Dimethylethyl hydroperoxide, TBHP, 2-Hydroperoxy-2-methylpropane
Linear Formula:
(CH3)3COOH
CAS Number:
Molecular Weight:
90.12
Beilstein/REAXYS Number:
1098280
MDL number:
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

quality

packed in FEP bottles

reaction suitability

reagent type: oxidant

concentration

~5.5 M in nonane (over molecular sieve 4 Å)

refractive index

n20/D 1.400

density

0.82 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

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Related Categories

Packaging

25, 100 mL in PFA/FEP bottle

Other Notes

Safe and stable oxidant for the Sharpless epoxidation

Reactant also used as a redox initiator and oxidant

Signal Word

Danger

Target Organs

Central nervous system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 3105A8 8(5.2)

WGK Germany

WGK 3

Flash Point(F)

84.2 °F - closed cup

Flash Point(C)

29 °C - closed cup

Certificate of Analysis

Certificate of Origin

K. Alagiri and K. R. Prabhu,
Tetrahedron, 67, 8544-8551 (2011)
X. Zhu, et al.,
Huaxue Xuebao, 69, 1107-1114 (2011)
B. Chaband, K.B. Sharpless
The Journal of Organic Chemistry, 44, 4202-4202 (1979)
Ramya Sivangala Thandi et al.
Nature communications, 11(1), 3535-3535 (2020-07-17)
Macrophages are professional phagocytes known to play a vital role in controlling Mycobacterium tuberculosis (Mtb) infection and disease progression. Here we compare Mtb growth in mouse alveolar (AMs), peritoneal (PMs), and liver (Kupffer cells; KCs) macrophages and in bone marrow-derived monocytes (BDMs)....
Younghwa Kim et al.
Food chemistry, 137(1-4), 136-141 (2012-12-04)
Oligomeric and polymeric procyanidins have been reported to possess different antioxidant capacities. However, the intracellular antioxidant mechanisms of oligomeric and polymeric procyanidins are still poorly understood. In this study, we evaluated the cytoprotective effects of the oligomeric procyanidin fraction (OPF)...

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