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201138

Sigma-Aldrich

Ammonium hexafluorophosphate

≥95%

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Synonym(s):
Ammonium hexafluophosphate, Ammonium hexafluorophosphate V, Ammonium phosphorus hexafluoride, Ammoniumhexafluorophosphate
Linear Formula:
NH4PF6
CAS Number:
Molecular Weight:
163.00
EC Number:
MDL number:
eCl@ss:
38070413
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

≥95%

form

solid

density

2.18 g/mL at 25 °C (lit.)

SMILES string

[H][N+]([H])([H])[H].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.H3N/c1-7(2,3,4,5)6;/h;1H3/q-1;/p+1

Inchi Key

NIZXKAYXSNUDOU-UHFFFAOYSA-O

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1 of 4

This Item
21599630402204749
vibrant-m

201138

Ammonium hexafluorophosphate

-
vibrant-m

215996

Ammonium phosphate dibasic

Essential Grade
vibrant-m

30402

Ammonium phosphate dibasic

Essential Grade
vibrant-m

204749

Ammonium hexafluorotitanate

-
Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

100

form

solid

form

crystals or chunks, powder

form

powder, crystals or granules

form

solid

density

2.18 g/mL at 25 °C (lit.)

density

-

density

-

density

-

application

Ammonium hexafluorophosphate (NH4PF6) can be used as a precursor for the preparation of:
  • Metal complexes, particularly iridium and rhodium complexes.       
  • Flame retardant cellulose-based materials.       
  • Cyclic amidinium and iminium ammonium hexafluorophosphate salts.        
  • The polymer-supported iridium isomerization catalyst for the selective trans isomerization of aryl allylic derivatives.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8B - Non-combustible, corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Preparation, crystal structures and spectroscopic properties of chloro (pentane-2, 4-dionato){1, 1, 1-tris (dimethylphosphinomethyl) ethane}chromium (III), cobalt (III) and rhodium (III) hexafluorophosphate: comparison of the M-P, M-Cl and M-O (M= Cr, Co a
Suzuki T, et al.
Polyhedron, 21(8), 835-841 (2002)
Ammonium Hexafluorophosphate as a Flame Retardant for Cellulose.
Mohamed, K Syed and Padma, DK
Journal of fire sciences, 5(1), 17-24 (1987)
A simple and efficient one-step protocol for the preparation of alkyl-substituted ammonium tetrafluoroborate and hexafluorophosphate salts
Saba Shahrokh, et al.
Journal of Fluorine Chemistry, 153, 168-171 (2013)
Homogeneous catalytic system for photoinduced hydrogen production utilizing iridium and rhodium complexes.
Cline, Eric D et al.
Inorganic Chemistry, 47(22), 10378-10388 (2008)
Accelerated luminophore discovery through combinatorial synthesis.
Lowry, Michael S et al.
Journal of the American Chemical Society, 126(43), 14129-14135 (2004)

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