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205699

Sigma-Aldrich

Palladium on carbon

greener alternative

extent of labeling: 10 wt. % loading, matrix activated carbon support

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Synonym(s):
Pd/C
Linear Formula:
Pd
Molecular Weight:
106.42
MDL number:
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22

form

powder

Quality Level

reaction suitability

core: palladium
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

extent of labeling

10 wt. % loading

matrix

activated carbon support

greener alternative category

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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1 of 4

This Item
520829205672237515
vibrant-m

205699

Palladium on carbon

vibrant-m

520829

Palladium on carbon

vibrant-m

205672

Palladium on carbon

vibrant-m

237515

Palladium on carbon

form

powder

form

-

form

powder

form

powder

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

extent of labeling

10 wt. % loading

extent of labeling

10 wt. % loading (dry basis)

extent of labeling

1 wt. % loading

extent of labeling

3 wt. % loading

matrix

activated carbon support

matrix

carbon powder, wet support

matrix

activated carbon support

matrix

activated carbon support

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Catalyst for:
  • Stille reaction
  • Hydrogenation reactions
  • Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions
  • Deoxygenation
  • Oxidation reactions
  • Coupling reactions
Palladium on carbon (Pd/C) (10 wt. % loading, matrix activated carbon support) can be used as a catalyst in the well known reactions like hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; dehydrogenate aromatics and deformylate aldehydes.
It can also be used as:

  • A catalyst for hydrodechlorination of dichlorodifluoromethane (CCl2F2), which is a known greenhouse gas,
  • A catalyst for Heck reactions of aryl halides in ionic liquids
  • An anode catalyst for the fabrication of direct formic acid fuel cells (DFAFC)
  • A cost-effective electrocatalyst for the oxidation of methanol
  • In the catalytic hydrogenation of chemical hydrides for the production of hydrogen
  • A catalyst in Suzuki-Mayaura reaction
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Characterisation of the deactivation of platinum and palladium supported on activated carbon used as hydrodechlorination catalysts
Ordonez S, et al.
Applied Catalysis. B, Environmental, 31(2), 113-122 (2001)
Physical and electrochemical characterizations of nanostructured Pd/C and PdNi/C catalysts for methanol oxidation
Liu Z, et al.
Electrochemical Communications, 11(4), 925-928 (2009)
Performance characterization of Pd/C nanocatalyst for direct formic acid fuel cells
Ha S, et al.
Journal of Power Sources, 144(1), 28-34 (2005)
Pd-C powder and thin film catalysts for hydrogen production by hydrolysis of sodium borohydride
Patel N, et al.
International Journal of Hydrogen Energy, 33(1), 287-292 (2008)
Heterogeneous Heck reaction catalyzed by Pd/C in ionic liquid
Hagiwara H, et al.
Tetrahedron Letters, 42(26), 4349-4351 (2001)

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