205796

Sigma-Aldrich

Potassium tetrachloropalladate(II)

98%

Synonym(s):
Potassium palladium(II) chloride
Linear Formula:
K2PdCl4
CAS Number:
Molecular Weight:
326.43
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

98%

form

crystalline

mp

105 °C (dec.) (lit.)

density

2.67 g/mL at 25 °C (lit.)

SMILES string

[K+].[K+].Cl[Pd--](Cl)(Cl)Cl

InChI

1S/4ClH.2K.Pd/h4*1H;;;/q;;;;2*+1;+2/p-4

InChI key

LGCKLDWLSVFMGL-UHFFFAOYSA-J

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Application

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.

Packaging

2, 10 g in glass bottle

Features and Benefits

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar. Reacts with bis(dithiolates) to metal-bis(dithiolates) with applications in laser Q-switch materials, optical CD recording media, bar code material and superconductivity.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
T N Semenets et al.
Radiatsionnaia biologiia, radioecologiia, 37(6), 892-895 (1998-02-19)
Efasol and potassium tetrachloropalladate being injected into mice prior to irradiation with a dose of 150 sGy increase the colony forming activity of animals bone marrow cells transplanted in lethally irradiated recipient mice. The palladium presence in such compounds is...
Hosny Ibrahim et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 23(5), 573-579 (2007-05-15)
A comparative study was made between developed chemically modified carbon paste electrodes and PVC membrane electrodes for the cationic surfactant cetyltrimethylammonium bromide (CTAB). The carbon paste electrode modified with cetyltrimethylammonium-tetrachloropalladate(II) (CTA-TClP) provides a more sensitive and stable device than that...
J Muris et al.
Allergy, 64(8), 1152-1156 (2009-02-12)
For patch testing, replacement of the commonly used palladium dichloride (PdCl2) by sodium tetrachloropalladate (Na2[PdCl4]) was recently demonstrated to improve test accuracy and show a significant correlation with nickel (Ni), supporting the concept of cross-reactivity between Pd and Ni. A...
R E Biagini et al.
Toxicology letters, 12(2-3), 165-170 (1982-07-01)
The effects of Na2PdCl4 were studied on isolated rat liver mitochondrial electron transport and oxidative phosphorylation in vitro. Significant reductions in ADP-stimulated respiration were observed with increasing Na2PdCl4 concentrations with both succinate and NADH-linked substrate oxidations. Concentration necessary for half-maximal...

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