208272

Vanadium(III) chloride

Name: Vanadium(III) chloride
Brand: ALDRICH
Price: 43.2 USD
Availability: InStock

97%

Synonym(s):

Vanadium trichloride

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$189.00

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$289.00

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About This Item

Linear Formula:

VCl₃

CAS Number:

7718-98-1

Molecular Weight:

157.30

NACRES:

NA.23

PubChem Substance ID:

24852503

UNSPSC Code:

12352302

EC Number:

231-744-6

MDL number:

MFCD00011454

Assay:

97%

Form:

powder

Key Documents

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InChI key

HQYCOEXWFMFWLR-UHFFFAOYSA-K

InChI

1S/3ClH.V/h3*1H;/q;;;+3/p-3

SMILES string

Cl[V](Cl)Cl

assay

97%

form

powder

reaction suitability

core: vanadium, reagent type: catalyst

density

3 g/mL at 25 °C (lit.)

Quality Level

100

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Catalysts

High-Purity Salts

Inorganic Catalysts

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Molten Salts

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Show Differences

1 of 4

This Item	422371	1.12393	395382
Sigma-Aldrich 208272 Vanadium(III) chloride	Sigma-Aldrich 422371 Vanadium(II) chloride	Sigma-Aldrich 1.12393 Vanadium(III) chloride	Sigma-Aldrich 395382 Vanadium(III) chloride tetrahydrofuran complex (1:3)
form powder	form powder	form solid	form powder
assay 97%	assay 85%	assay -	assay 97%
Quality Level 100	Quality Level 100	Quality Level 200	Quality Level 100
density 3 g/mL at 25 °C (lit.)	density 3.09 g/mL at 25 °C (lit.)	density 3.0 g/cm³ at 20 °C	density -
reaction suitability reagent type: catalyst core: vanadium	reaction suitability reagent type: catalyst core: vanadium	reaction suitability -	reaction suitability reagent type: catalyst core: vanadium
application(s) battery manufacturing	application(s) battery manufacturing	application(s) -	application(s) battery manufacturing

General description

Vanadium(III) chloride is a crystalline solid with variable oxidation states. It is widely used as a catalyst in organic synthesis, polymerization processes, and redox batteries. It acts as a reducing agent.

Application

Vanadium chloride may be used as a reduction agent to determine nitrates and nitrites in water samples.[1]It may be used in redox flow batteries.[2] Vanadium trichloride catalyses Pinacol coupling reactions of benzaldehyde in water.[3] it also acts as a mild and efficient catalyst for the chemoselective deprotection of acetonides.[4]

pictograms

GHS05,GHS07

signalword

Danger

hcodes

H302,H314

pcodes

P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH014

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Mechanisms of Specific Embryonic Effects of Nitrogen Oxide.

A M Dolgorukova et al.

Bulletin of experimental biology and medicine, 165(5), 635-639 (2018-09-19)

The study of NO metabolism in chicken embryos showed that the intensity of oxidation of both endogenous and exogenous for the embryo NO donors to nitrate is determined by the presence or state of NO targets, rather than donor concentration.

Gastroprotective effect of desmosdumotin C isolated from Mitrella kentii against ethanol-induced gastric mucosal hemorrhage in rats: possible involvement of glutathione, heat-shock protein-70, sulfhydryl compounds, nitric oxide, and anti-Helicobacter pylori activity.

Heyam Mohamed Ali Sidahmed et al.

BMC complementary and alternative medicine, 13, 183-183 (2013-07-23)

Mitrella kentii (M. kentii) (Bl.) Miq, is a tree-climbing liana that belongs to the family Annonaceae. The plant is rich with isoquinoline alkaloids, terpenylated dihydrochalcones and benzoic acids and has been reported to possess anti-inflammatory activity. The purpose of this

Novel vanadium chloride/polyhalide redox flow battery.

Skyllas-Kazacos M

Journal of Power Sources, 124(1), 299-302 (2003)

Quillaja saponaria bark saponin protects Wistar rats against ferrous sulphate-induced oxidative and inflammatory liver damage.

Mustafa Ahmed Abdel-Reheim et al.

Pharmaceutical biology, 55(1), 1972-1983 (2017-07-22)

Saponins from different sources are historically reported in Chinese medicine to possess many beneficial effects. However, insufficient experimental data are available regarding the hepatoprotective potential of Quillaja bark saponin. The protective effect of Quillaja saponaria Molina (Quillajaceae) bark triterpenoid saponin

Thermal Instability Induced Oriented 2D Pores for Enhanced Sodium Storage.

Lingjun Kong et al.

Small (Weinheim an der Bergstrasse, Germany), 14(21), e1800639-e1800639 (2018-04-20)

Hierarchical porous structures are highly desired for various applications. However, it is still challenging to obtain such materials with tunable architectures. Here, this paper reports hierarchical nanomaterials with oriented 2D pores by taking advantages of thermally instable bonds in vanadium-based

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Vanadium(III) chloride