208329

Sigma-Aldrich

Sodium amide

greener alternative

98%

Linear Formula:
NaNH2
CAS Number:
Molecular Weight:
39.01
EC Number:
MDL number:
PubChem Substance ID:

Quality Level

assay

98%

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

bp

400 °C (lit.)

mp

210 °C (lit.)

SMILES string

N[Na]

InChI

1S/H2N.Na/h1H2;/q-1;+1

InChI key

ODZPKZBBUMBTMG-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Reagent for:
Synthesis of allylic amines and amides
Synthesis of antibacterials
Aggregative activation and heterocyclic chemistry
Phenylation with diphenyliodonium chloride
Sodium amide (NH2Na) (98%) can be used for a variety of applications such as:
  • production of a hydrogen storage system
  • adsorption of CO2
  • fabrication of fuel cells

Packaging

50, 250 g in glass bottle
1 kg in glass bottle

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

hazcat

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - Water-react. 2

Supp Hazards

EUH014 - EUH019 - EUH029

storage_class_code

4.3 - Hazardous materials, which set free flammable gases upon contact with water

WGK Germany

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

K. G. Hampton, et al.,
Organic Syntheses, 51, 128-132 (1971)
Hydrogen production from ammonia using sodium amide
David WIF, et al.
Journal of the American Chemical Society, 136(38), 13082-13085 (2014)
M. Bakavoli, et al.,
Journal of Heterocyclic Chemistry, 48, 149-152 (2010)
The reactions in LiBH4-NaNH2 hydrogen storage system
Zhang Y and Tian Q
International Journal of Hydrogen Energy, 36(16), 9733-9742 (2011)
C. Caubere, et al.,
Tetrahedron, 50, 11903-11920 (1994)

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