208353

Sigma-Aldrich

Molybdenum(V) chloride

95%

Linear Formula:
MoCl5
CAS Number:
Molecular Weight:
273.21
MDL number:
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

Quality Level

vapor pressure

1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)

assay

95%

form

powder

reaction suitability

reagent type: catalyst
core: molybdenum

impurities

<0.5% insoluble matter

bp

268 °C (lit.)

mp

194 °C (lit.)

density

2.928 g/mL at 25 °C (lit.)

Featured Industry

Battery Manufacturing

SMILES string

Cl[Mo](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

InChI key

GICWIDZXWJGTCI-UHFFFAOYSA-I

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Application

Hexaalkoxytriphenylenes are obtained from o-dialkoxybenzenes by oxidative trimerization using MoCl5.

Packaging

25, 100 g in glass bottle

Pictograms

CorrosionHealth hazard

Signal Word

Danger

Hazard Statements

Hazard Codes

C

Risk Statement

29-34-40

Safety Statement

26-36/37/39-45

RIDADR

UN 2508 8 / PGIII

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Kumar, S. Manickam, M.
Chemical Communications (Cambridge, England), 1615-1615 (1997)
H I Ogawa et al.
Mutation research, 320(1-2), 133-140 (1994-01-01)
A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the third instar stage with a test compound and...
Mladen Litvić et al.
Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)
Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose...
Kristina Hackeloer et al.
Organic letters, 13(5), 916-919 (2011-02-02)
A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated.
Simon Trosien et al.
Organic letters, 14(12), 2976-2979 (2012-06-05)
The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular...
Articles
In the last two decades, a new method termed solid-state metathesis (SSM) has been developed to synthesize compounds that are often difficult to produce conventionally.
Read More

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