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208930
Tin(IV) chloride
98%
Synonym(s):
Stannic chloride fuming
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$89.10
$424.00
About This Item
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Product Name
Tin(IV) chloride, 98%
InChI key
HPGGPRDJHPYFRM-UHFFFAOYSA-J
InChI
1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
SMILES string
Cl[Sn](Cl)(Cl)Cl
vapor density
9 (vs air)
vapor pressure
10 mmHg ( 10 °C)
18.6 mmHg ( 20 °C)
20 mmHg ( 22 °C)
assay
98%
form
liquid
reaction suitability
core: tin
reagent type: Lewis acid
reagent type: catalyst
bp
114 °C (lit.)
mp
−33 °C (lit.)
density
2.226 g/mL at 25 °C (lit.)
Quality Level
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This Item | 217913 | 1.07810 | 249955 |
|---|---|---|---|
| reaction suitability core: tin, reagent type: catalyst, reagent type: Lewis acid | reaction suitability core: tin, reagent type: Lewis acid, reagent type: catalyst | reaction suitability - | reaction suitability core: tin, reagent type: catalyst |
| assay 98% | assay 99.995% trace metals basis | assay ≥99.0% (acidimetric) | assay - |
| form liquid | form liquid | form liquid | form liquid |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 100 |
| mp −33 °C (lit.) | mp −33 °C (lit.) | mp -33 °C | mp - |
| bp 114 °C (lit.) | bp 114 °C (lit.) | bp 114 °C/1013 hPa | bp - |
Application
- Cyclization of trans β-monocyclohomofarnesic acid to form norambreinolide.[1]
- Formation of C-glycosides of aromatic compounds such as thiophene, naphthalene and phloroglucinol trimethyl ether.[2]
- Formal [4+2] cycloaddition of 3-ethoxycyclobutanones and allyltrialkylsilanes to form 3-ethoxy-5-[(trialkylsilyl)methyl]cyclohexan-1-ones.[3]
- Diastereoselective reaction of δ-alkoxyallylstannanes with aldehydes to form 1,5-diol derivatives.[4]
Other applications of SnCl4:
- The SnCl4-2,6-dialkoxyphenols complexes can catalyze cyclization of poylenes, such as 4-(homogeranyl)toluene to form trans-fused tricyclic compound.[5]
- SnCl4 can act as a promoter during the reaction of ortho-aminobenzonitriles with β-ketoesters and β-enaminonitriles to form 4-aminoquinolines and 4-aminopyridines, respectively.[6]
- SnCl4-silver perchlorate forms an effective catalytic system for the stereoselective of glycosylation 1-O-acetyl glucose.[7]
General description
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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