208930
Tin(IV) chloride
98%
Recommended Products
vapor density
9 (vs air)
Quality Level
vapor pressure
10 mmHg ( 10 °C)
18.6 mmHg ( 20 °C)
20 mmHg ( 22 °C)
Assay
98%
form
liquid
reaction suitability
core: tin
reagent type: Lewis acid
reagent type: catalyst
bp
114 °C (lit.)
mp
−33 °C (lit.)
density
2.226 g/mL at 25 °C (lit.)
SMILES string
Cl[Sn](Cl)(Cl)Cl
InChI
1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
InChI key
HPGGPRDJHPYFRM-UHFFFAOYSA-J
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This Item | 249955 | 1.07810 | 244678 |
|---|---|---|---|
| assay 98% | assay - | assay ≥99.0% (acidimetric) | assay 98% |
| form liquid | form liquid | form liquid | form powder or chunks |
| reaction suitability core: tin, reagent type: Lewis acid, reagent type: catalyst | reaction suitability core: tin, reagent type: catalyst | reaction suitability - | reaction suitability - |
| bp 114 °C (lit.) | bp - | bp 114 °C/1013 hPa | bp - |
| mp −33 °C (lit.) | mp - | mp -33 °C | mp - |
| density 2.226 g/mL at 25 °C (lit.) | density 1.419 g/mL at 25 °C | density 2.23 g/cm3 at 20 °C | density - |
General description
Application
- Cyclization of trans β-monocyclohomofarnesic acid to form norambreinolide.
- Formation of C-glycosides of aromatic compounds such as thiophene, naphthalene and phloroglucinol trimethyl ether.
- Formal [4+2] cycloaddition of 3-ethoxycyclobutanones and allyltrialkylsilanes to form 3-ethoxy-5-[(trialkylsilyl)methyl]cyclohexan-1-ones.
- Diastereoselective reaction of δ-alkoxyallylstannanes with aldehydes to form 1,5-diol derivatives.
Other applications of SnCl4:
- The SnCl4-2,6-dialkoxyphenols complexes can catalyze cyclization of poylenes, such as 4-(homogeranyl)toluene to form trans-fused tricyclic compound.
- SnCl4 can act as a promoter during the reaction of ortho-aminobenzonitriles with β-ketoesters and β-enaminonitriles to form 4-aminoquinolines and 4-aminopyridines, respectively.
- SnCl4-silver perchlorate forms an effective catalytic system for the stereoselective of glycosylation 1-O-acetyl glucose.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
8A - Combustible, corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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