213403
N-Selectride®
1.0 M in THF
Synonym(s):
Sodium tri-sec-butylborohydride solution
About This Item
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form
liquid
Quality Level
reaction suitability
reagent type: reductant
concentration
1.0 M in THF
density
0.893 g/mL at 25 °C (lit.)
SMILES string
[Na+].CCC(C)[BH-](C(C)CC)C(C)CC
InChI
1S/C12H28B.Na/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
InChI key
JUFGMKFPFVIKOY-UHFFFAOYSA-N
Related Categories
1 of 4
This Item | 220760 | 178497 | 255793 |
|---|---|---|---|
| reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability - |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 100 |
| form liquid | form liquid | form liquid | form solid |
| density 0.893 g/mL at 25 °C (lit.) | density 0.913 g/mL at 25 °C | density 0.89 g/mL at 25 °C | density - |
| concentration 1.0 M in THF | concentration 1.0 M potassium tri-sec-butylborohydride in THF | concentration 1.0 M in THF | concentration - |
Application
- Reducing agent
Reactant for:
- Conjugate hydride reduction-initiated tandem cyclization reactions
- Sereoselective nucleophilic addition reactions
Legal Information
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk_germany
WGK 3
flash_point_f
5.0 °F - closed cup
flash_point_c
-15 °C - closed cup
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