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218170

Sigma-Aldrich

Ethynyltrimethylsilane

98%

Synonym(s):

Trimethylsilylacetylene

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1 G
$37.50
5 G
$69.10
25 G
$144.00
100 G
$508.00

About This Item

Linear Formula:
(CH3)3SiC≡CH
CAS Number:
Molecular Weight:
98.22
Beilstein/REAXYS Number:
906752
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

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$37.50


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vapor pressure

4.18 psi ( 20 °C)

Quality Level

assay

98%

form

liquid

refractive index

n20/D 1.388 (lit.)

bp

53 °C (lit.)

density

0.709 g/cm3 (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(C)C#C

InChI

1S/C5H10Si/c1-5-6(2,3)4/h1H,2-4H3

InChI key

CWMFRHBXRUITQE-UHFFFAOYSA-N

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1 of 4

This Item
422150196681523380
assay

98%

assay

98%

assay

99%

assay

97%

Quality Level

200

Quality Level

-

Quality Level

100

Quality Level

200

bp

53 °C (lit.)

bp

-

bp

80-81 °C/20 mmHg (lit.)

bp

-

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-

density

0.709 g/cm3 (lit.)

density

-

density

1.278 g/mL at 25 °C (lit.)

density

-

refractive index

n20/D 1.388 (lit.)

refractive index

-

refractive index

n20/D 1.4583 (lit.)

refractive index

-

General description

Laser-induced polymerization of gaseous ethynyltrimethylsilane was used for efficient chemical vapour deposition of polycarbosilane films[1]. Ethynyltrimethylsilane acts as substrate for nickel-catalyzed cross-coupling with benzonitriles[2].

Application

Ethynyltrimethylsilane was used in:
  • microwave-assisted, one-pot, three-step Sonogashira cross-coupling-desilylation-cycloaddition reaction for the preparation of 1,4-disubstituted 1,2,3-triazoles[3]
  • synthesis of poly(ethynyltrimethylsilane) containing Pd (II) coordination sites[4]
  • pyrazole synthesis via 1,3-dipolar cycloaddition of diazo compounds to acetylenes[5]

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

-29.2 °F

flash_point_c

-34 °C

ppe

Faceshields, Gloves, Goggles


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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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