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Titanium(III) chloride

ReagentPlus®, powder

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Synonym(s):
Titanium trichloride
Linear Formula:
TiCl3
CAS Number:
Molecular Weight:
154.23
EC Number:
MDL number:
PubChem Substance ID:

product line

ReagentPlus®

form

powder

reaction suitability

reagent type: catalyst
core: titanium

mp

440 °C (dec.) (lit.)

SMILES string

Cl[Ti](Cl)Cl

InChI

1S/3ClH.Ti/h3*1H;/q;;;+3/p-3

InChI key

YONPGGFAJWQGJC-UHFFFAOYSA-K

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Application

Used for the vapor-phase formation of intermetallic compounds with ultrafine particle size.
Used with tert-butylhydroperoxide in an alcoholic solvent to promote the reductive coupling of aryl aldehydes to 1,2-diols.

Catalyst for:
hydrogen desorption properties
Nitrogen-nitrogen reductive bond cleavage

Reagent for photocatalyst synthesis

Precursor for the preparation of nanostructures titania/cetyltrimethyammonium bromide nanoskeletons

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Pyr. Sol. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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European Journal of Organic Chemistry, 4050-4050 (2007)
S. Isobe, et al.,
Applied Physics Letters, 99 (2011)
D. Meroni, et al
Catalysis Today, 161, 169-174 (2011)
Shuxi Dai et al.
Nanoscale research letters, 5(11), 1829-1835 (2010-12-03)
Highly crystalline TiO(2) nanostructures were prepared through a facile inorganic acid-assisted hydrothermal treatment of hexagonal-structured assemblies of nanocrystalline titiania templated by cetyltrimethylammonium bromide (Hex-ncTiO(2)/CTAB Nanoskeleton) as starting materials. All samples were characterized by X-ray diffraction (XRD) and transmission electron microscopy
Gnana S Siluvai et al.
Biochemistry, 48(51), 12133-12144 (2009-11-20)
Sco-like proteins contain copper bound by two cysteines and a histidine residue. Although their function is still incompletely understood, there is a clear involvement with the assembly of cytochrome oxidases that contain the Cu(A) center in subunit 2, possibly mediating

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