221759

Sigma-Aldrich

Ammonium cerium(IV) sulfate dihydrate

Synonym(s):
Cerium(IV) ammonium sulfate, Ceric ammonium sulfate
Linear Formula:
Ce(NH4)4(SO4)4 · 2H2O
CAS Number:
Molecular Weight:
632.55
MDL number:
PubChem Substance ID:

Quality Level

assay

≥94.0% (with KMnO4, redox titration)

form

powder

composition

Ce(IV), ≥20%

reaction suitability

reagent type: catalyst
core: cerium

mp

130 °C (lit.)

SMILES string

N.N.N.N.O.O.[Ce+4].OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O

InChI

1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;4*1-5(2,3)4;;/h;4*1H3;4*(H2,1,2,3,4);2*1H2/q+4;;;;;;;;;;/p-4

InChI key

VCNAMBGKEDPVGQ-UHFFFAOYSA-J

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Application

The product may be used to initiate the radical polymerization of pectin-poly(ethylene glycol) methacrylate (PEGMA) supracmolecular hydrogels. Ammonium cerium sulphate impregnated starch may be carbonized to form cerium dispersed carbon (CeDC) sorbent used for the extraction of excess fluoride in drinking water.

Packaging

100, 500 g in poly bottle

storage_class_code

13 - Non Combustible Solids

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Cerium dispersed in carbon (CeDC) and its adsorption behavior: A first example of tailored adsorbent for fluoride removal from drinking water
Sivasankar V, et al.
Chemical Engineering Journal, 214, 45-54 (2013)
Thixotropic Supramolecular Pectin-Poly (Ethylene Glycol) Methacrylate (PEGMA) Hydrogels.
Chan SY, et al.
Polymer, 8(11), 404-404 (2016)
K H Gordon et al.
Organic letters, 3(1), 53-56 (2001-06-30)
[figure: see text] A novel benzyloxyaniline linker that uses ceric ammonium nitrate (CAN) as a cleavage reagent is described. Its application in the solid-phase synthesis of N-unsubstituted beta-lactams and secondary amides furnishes compounds in moderate to excellent yield (45-91%) and...
Effect of high room temperature on urinary iodine assay.
N T Dung et al.
Clinical chemistry, 43(6 Pt 1), 1084-1085 (1997-06-01)
Babu G Gowda et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 18(6), 671-674 (2002-06-27)
Two simple and sensitive indirect spectrophotometric methods for the assay of propranolol hydrochloride (PPH) and piroxicam (PX) in pure and pharmaceutical formulations have been proposed. The methods are based on the oxidation of PPH by a known excess of standard...

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