223662

Sigma-Aldrich

Tris(triphenylphosphine)ruthenium(II) dichloride

97%

Synonym(s):
Tris(triphenylphosphine)dichlororuthenium, Dichlorotris(triphenylphosphine)ruthenium(II), Ruthenium(II)-tris(triphenylphosphine) dichloride
Linear Formula:
(C6H5)3P3RuCl2
CAS Number:
Molecular Weight:
958.83
Beilstein/REAXYS Number:
4935939
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

97%

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: C-H Activation

SMILES string

ClRuCl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2

InChI key

WIWBLJMBLGWSIN-UHFFFAOYSA-L

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Packaging

1, 5, 25 g in glass bottle

Application

  • Catalyst employed in a synthesis of furans from allenyl sulfides.
  • C-H Activation Catalyst in a Ruthenium/Lewis Acid System

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

Xn

Risk Statement

20/21/22

Safety Statement

36/37

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Cross-coupling reaction between alcohols through sp3 C-H activation catalyzed by a ruthenium/Lewis acid system.
Shu-Yu Zhang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(33), 10201-10205 (2008-10-11)
Transition-metal-catalyzed rearrangement of allenyl sulfides: a route to furan derivatives.
Lingling Peng et al.
Angewandte Chemie (International ed. in English), 46(11), 1905-1908 (2007-02-03)

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