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224308

Dilithium tetrachlorocuprate(II) solution

0.1 M in THF

Synonym(s):

Copper dilithium tetrachloride, Dilithium tetrachlorocuprate(2-), Lithium Tetrachlorocuprate

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$288.00

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$382.00

$288.00

Estimated to ship onJanuary 12, 2026Details

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About This Item

Linear Formula:
Li2CuCl4
CAS Number:
15489-27-7
Molecular Weight:
219.24
NACRES:
NA.23
PubChem Substance ID:
24853427
UNSPSC Code:
12352302
EC Number:
203-726-8
MDL number:
MFCD00011081
Form:
liquid

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Product Name

Dilithium tetrachlorocuprate(II) solution, 0.1 M in THF

InChI key

HCJWWBBBSCXJMS-UHFFFAOYSA-J

InChI

1S/4ClH.Cu.2Li/h4*1H;;;/q;;;;+2;2*+1/p-4

SMILES string

[Li+].[Li+].Cl[Cu--](Cl)(Cl)Cl

form

liquid

reaction suitability

reagent type: catalyst

concentration

0.1 M in THF

density

0.91 g/mL at 25 °C

application(s)

battery precursors
catalysts
material synthesis precursor

Quality Level

100

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1 of 4

This Item
697257398195703524
Dilithium tetrachlorocuprate(II) solution 0.1 M in THF

Sigma-Aldrich

224308

Dilithium tetrachlorocuprate(II) solution

Copper(I) cyanide di(lithium chloride) complex solution in anhydrous tetrahydrofuran

Sigma-Aldrich

697257

Copper(I) cyanide di(lithium chloride) complex solution

Lithium tert-butoxide solution 1.0 M in THF

Sigma-Aldrich

398195

Lithium tert-butoxide solution

Lithium tert-amoxide solution 40 % (w/w) in heptanes

Sigma-Aldrich

703524

Lithium tert-amoxide solution

form

liquid

form

liquid

form

liquid

form

liquid

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

density

0.91 g/mL at 25 °C

density

0.999 g/mL at 25 °C

density

0.888 g/mL at 25 °C

density

0.73 g/mL at 25 °C

reaction suitability

reagent type: catalyst
core: copper

reaction suitability

-

reaction suitability

-

reaction suitability

-

concentration

0.1 M in THF

concentration

in anhydrous tetrahydrofuran

concentration

1.0 M in THF

concentration

40 % (w/w) in heptanes, ~3.1 M in heptane

Application

Catalyst used to couple alkyl halides with alkyl Grignard reagents.[1]

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX7134
MKCQ7865
MKCM6669
SHBH5044V
SHBF1928V

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Kenji Mori
Bioscience, biotechnology, and biochemistry, 74(3), 595-600 (2010-03-09)
A mixture of the four stereoisomers of 1,7-dimethylnonyl propanoate, the female sex pheromone of the western corn rootworm (Diabrotica virgifera virgifera LeConte), was synthesized in four different ways by employing one of the following four reactions as the key step:
Tetrahedron, 62, 4851-4851 (2006)
K Minamoto et al.
Nucleic acids symposium series, (27)(27), 109-110 (1992-01-01)
The reaction of 1-(2,3-anhydro-5-O-trityl-beta-D-lyxofuranosyl)-2-O-methyluracil (1a) and its thymine analogue (1b) with dilithium tetrahalocuprate (Li2CuX4) revealed excellent to perfect regioselectivity, yielding 2,2'-anhydro-3'-halonucleosides (2a-d), while the same reactions with 2,3-anhydro uracil and thymine nucleosides (4a,b) gave arabinosyl (5a-d) and xylosyl halohydrins (6a-d)

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