If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
224839
Bismuth(III) chloride
reagent grade, ≥98%
Synonym(s):
Bismuth trichloride, Trichlorobismuth
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
25 g | Estimated to ship onJuly 06, 2026fromMILWAUKEE | $132.00 |
100 g | Estimated to ship onJuly 06, 2026fromMILWAUKEE | $369.00 |
500 g | Estimated to ship onJuly 06, 2026fromMILWAUKEE | $1,320.00 |
About This Item
grade
reagent grade
Quality Segment
assay
≥98%
form
powder, chunks or granules
reaction suitability
reagent type: catalyst
core: bismuth
bp
447 °C (lit.)
mp
230-232 °C (lit.)
SMILES string
Cl[Bi](Cl)Cl
InChI
1S/Bi.3ClH/h;3*1H/q+3;;;/p-3
InChI key
JHXKRIRFYBPWGE-UHFFFAOYSA-K
General description
Application
- Alcoholysis, acetolysis and hydrolysis of epoxides to form the corresponding β-alkoxy and β-acetoxy alcohols and diols.
- Preparation of thiiranes from oxiranes using ammonium thiocyanate.
- Three component coupling of carbonyl compound, amine and dialkyl phosphite to form α-amino phosphonates.
- Allylation of secondary benzyl alcohols with allyltrimethylsilane.
- [4 + 2] cycloaddition between dienes and α-carbonyl ethylenic dienophiles.
1 of 1
This Item | |||
|---|---|---|---|
| form powder, chunks or granules | form solid | form powder | form - |
| assay ≥98% | assay 99.99% trace metals basis | assay 99.998% trace metals basis | assay 99.999% trace metals basis |
| grade reagent grade | grade - | grade anhydrous | grade synthesis grade |
| mp 230-232 °C (lit.) | mp 230-232 °C (lit.) | mp 230-232 °C (lit.) | mp 230-232 °C (lit.) |
| bp 447 °C (lit.) | bp 447 °C (lit.) | bp 447 °C (lit.) | bp 447 °C (lit.) |
| reaction suitability reagent type: catalyst | reaction suitability - | reaction suitability - | reaction suitability - |
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signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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