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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
225584
Vinylmagnesium bromide solution
1.0 M in THF
Synonym(s):
Bromoethenylmagnesium, Bromovinylmagnesium
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About This Item
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Quality Level
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF
density
0.981 g/mL at 25 °C
SMILES string
Br[Mg]C=C
InChI
1S/C2H3.BrH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1
InChI key
XHHHAXOHMKAOSL-UHFFFAOYSA-M
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Related Categories
1 of 4
This Item | 257257 | 476552 | 346152 |
|---|---|---|---|
| reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction |
| density 0.981 g/mL at 25 °C | density 0.981 g/mL at 25 °C | density 0.978 g/mL at 25 °C | density 0.94 g/mL at 25 °C |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| concentration 1.0 M in THF | concentration 1.0 M in THF | concentration 1.6 M in THF | concentration 0.5 M in THF |
Application
It may also be used in the following transformations:
- (S)-3-(benzyloxy)-4-oxo-butanoic acid methyl ester to methyl (3S,4S)-4-hydroxy-3-(phenylmethoxy)hex-5-enoate.[2]
- (R)-1-Azido-5,6-epoxyhexane to (S)-1-(4-azidobutyl)-2-propen-1-ol.[3]
- 2,3-O-Isopropylidene-D-ribose to 1-[(4R,5S)-5-((1S)-1-hydroxyallyl)-2,2-dimethyl[1,3]dioxolan-4-yl]ethane-1,2-diol.[4]
- (4S,5S)-2,2-Dimethyl-5-vinyl[1,3]dioxolane-4-carbaldehyde to (1R,4R,5S)- and (1S,4R,5S)-1-(2,2-dimethyl-5-vinyl[1,3]dioxolan-4-yl)prop-2-en-1-ol.[4]
- Ethyl levulinate to ?-methyl-?-vinylbutyrolactone.[5]
Packaging
Other Notes
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3 - Water-react 1
target_organs
Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk_germany
WGK 1
flash_point_f
1.4 °F
flash_point_c
-17.0 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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