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Sigma-Aldrich

Tris(triphenylphosphine)rhodium(I) carbonyl hydride

97%

Synonym(s):
Carbonyltris(triphenylphosphine)rhodium(I) hydride, Rhodium monocarbonyl hydrogen tris(triphenylphosphine), Rhodium(I) tris(triphenylphosphine) carbonyl hydride, trans-Carbonyl(hydrido)tris(triphenylphosphine)rhodium, Hydridocarbonyl-tris(triphenylphosphine)-rhodium(I), RhH(CO)(PPh3)3, Tris(triphenylphosphine)carbonylrhodium hydride
Linear Formula:
[(C6H5)3P]3Rh(CO)H
CAS Number:
Molecular Weight:
918.78
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

form

solid

reaction suitability

core: rhodium
reagent type: catalyst

mp

150 °C (dec.) (lit.)

SMILES string

[RhH].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.CO.Rh.H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;;

InChI key

AACIZACVKFEETJ-UHFFFAOYSA-N

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Packaging

5 g in glass bottle
500 mg in amber glass bottle

Application

Catalyzes the ring-opening isomeriztion of methylenecyclopropanes to 1,3-dienes.

Features and Benefits

Homogeneous catalyst.

Storage Class Code

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

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Certificate of Origin

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