225789

Sigma-Aldrich

Chloroform-d

99.8 atom % D, contains 0.03 % (v/v) TMS

Synonym(s):
Deuterochloroform
Linear Formula:
CDCl3
CAS Number:
Molecular Weight:
120.38
Beilstein/REAXYS Number:
1697633
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.21

Quality Level

isotopic purity

99.8 atom % D

assay

≥99% (CP)

form

liquid

contains

0.03 % (v/v) TMS

application(s)

NMR: suitable

impurities

≤0.0100% water
water

refractive index

n20/D 1.444 (lit.)

bp

60.9 °C (lit.)

mp

−64 °C (lit.)

density

1.500 g/mL at 25 °C (lit.)

mass shift

M+1

SMILES string

[2H]C(Cl)(Cl)Cl

InChI

1S/CHCl3/c2-1(3)4/h1H/i1D

InChI key

HEDRZPFGACZZDS-MICDWDOJSA-N

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General description

Chloroform-d is a deuterated NMR solvent useful in NMR-based research and analyses.

Application

Chloroform-d may be used in the synthesis of dichlorofluoromethane-d (DCFM).

Packaging

150 g in Sure/Seal™
500 g in glass bottle
10×0.6, 10×1 mL in ampule
50, 100 g in glass bottle

Pictograms

Skull and crossbonesHealth hazard

Signal Word

Danger

Target Organs

Central nervous system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 1888 6.1 / PGIII

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

Dichlorofluoromethane-d: a versatile solvent for VT-NMR experiments.
Siegel JS & Anet, FA
The Journal of Organic Chemistry, 53(11), 2629-2630 (1988)
Salvatore Barreca et al.
Natural product research, 33(7), 947-955 (2015-11-28)
This preliminary study has mainly focused on the wax identification by nuclear magnetic resonance (NMR) and removal. Wax is used for many purposes in the field of art as protective coatings on wooden, stone or metal objects. From the comparison...
Isotopic dilution studies of the chloroform-chloroform-d system by Raman difference spectroscopy.
Laane J and Kiefer W.
J. Chem. Phys. , 73(10), 4971-4975 (1980)
Quantitative Study of the Bonding of Chloroform-d in Various Solvents by Infrared Spectrometry1.
Lord RC, et al.
Journal of the American Chemical Society, 77(5), 1365-1368 (1955)
Dichlorofluoromethane-d: a versatile solvent for VT-NMR experiments.
Siegel JS and Anet FAL.
The Journal of Organic Chemistry, 53(11), 2629-2630 (1988)
Related Content
NMR spectroscopy is an analytic technique to determine molecular structure, chemical composition and purity. NMR detects the energy absorbed due to nuclear spin states in the presence of a strong magnetic field.
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