227234

2-Mesitylmagnesium bromide solution

1.0 M in THF

• Synonym(s): 2,4,6-Trimethylphenylmagnesium bromide
• Linear Formula: (CH₃)₃C₆H₂MgBr
• CAS Number: 2633-66-1
• Molecular Weight: 223.39
• MDL number: MFCD00009663
• PubChem Substance ID: 24853266
• NACRES: NA.22

Properties

• Quality Level: 100
• reaction suitability: reaction type: Grignard Reaction
• concentration: 1.0 M in THF
• density: 1.005 g/mL at 25 °C
• SMILES string: Cc1cc(C)c([Mg]Br)c(C)c1
• InChI: 1S/C9H11.BrH.Mg/c1-7-4-8(2)6-9(3)5-7;;/h4-5H,1-3H3;1H;/q;;+1/p-1
• InChI key: YXVSITSUDRGILL-UHFFFAOYSA-M

Description

Application

2-Mesitylmagnesium bromide is a Grignard reagent generally used to synthesize stable aromatic radical species such as dibenzoheptazethrene, diindenoanthracene, teranthene and dimesitylindeno[2,1-a]fluorene by kinetically blocking reactive molecular sites. It is also used in a variety of aromatic cross-coupling reactions.

Safety Information

• Pictograms: GHS02,GHS05,GHS07,GHS08
• Signal Word: Danger
• Hazard Statements: H225 - H314 - H335 - H336 - H351
• Precautionary Statements: P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
• Supplementary Hazards: EUH014 - EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 1.4 °F - closed cup
• Flash Point(C): -17.0 °C - closed cup