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227722

Sigma-Aldrich

Silver hexafluorophosphate

98%

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Synonym(s):
Silver(I) hexafluorophosphate
Linear Formula:
AgPF6
CAS Number:
Molecular Weight:
252.83
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

98%

form

solid

reaction suitability

core: silver
reagent type: catalyst

mp

102 °C (dec.) (lit.)

SMILES string

[Ag+].F[P-](F)(F)(F)(F)F

InChI

1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1

InChI key

SCQBROMTFBBDHF-UHFFFAOYSA-N

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1 of 4

This Item
208361225673450219
vibrant-m

227722

Silver hexafluorophosphate

-
vibrant-m

208361

Silver tetrafluoroborate

-
vibrant-m

225673

Silver sulfate

Essential Grade
vibrant-m

450219

Silver hexafluorophosphate

-
reaction suitability

core: silver, reagent type: catalyst

reaction suitability

core: silver, reagent type: catalyst

reaction suitability

-

reaction suitability

-

form

solid

form

-

form

lumps and powder

form

powder

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

100

mp

102 °C (dec.) (lit.)

mp

70-73 °C (lit.)

mp

652 °C (lit.)

mp

102 °C (dec.) (lit.)

General description

Silver hexafluorophosphate can be used as a catalyst for the sulfimidation, hydrogenation of aldehydes to alcohols, and hydroacyloxylation of alkynes with carboxylic acids.

Application

Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials. Preparation of supramolecular networks of Ag(I) complexes.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Gold (I)-catalyzed addition of carboxylic acids to alkynes
Chary B, et al.
The Journal of Organic Chemistry, 75, 7928-7931 (2010)
Silver-Catalyzed Hydrogenation of Aldehydes in Water
Jia Z, et al.
Angewandte Chemie (International Edition in English), 52, 11871-11874 (2013)
Journal of Organometallic Chemistry, 692, 4093-4093 (2007)
Silver-Catalyzed Enantioselective Sulfimidation Mediated by Hydrogen Bonding Interactions
Annapureddy R, et al.
Angewandte Chemie (International Edition in English), 133, 7999-8005 (2021)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

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