235083

Sigma-Aldrich

Sodium bis(trimethylsilyl)amide

95%

Synonym(s):
Hexamethyldisilazane sodium salt
Linear Formula:
[(CH3)3Si]2NNa
CAS Number:
Molecular Weight:
183.37
Beilstein/REAXYS Number:
3629917
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

95%

mp

171-175 °C (lit.)

SMILES string

C[Si](C)(C)N([Na])[Si](C)(C)C

InChI

1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key

WRIKHQLVHPKCJU-UHFFFAOYSA-N

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Related Categories

Application

Useful for the generation of carbenes, the amination of sulfenamides, and the preparation of lanthanide complexes.

Packaging

5, 25, 100 g in glass bottle

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

hazcat

Skin Corr. 1B

Supp Hazards

EUH014

storage_class_code

8A - Combustible, corrosive hazardous materials

WGK Germany

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Journal of the American Chemical Society, 116, 7637-7637 (1994)
Angewandte Chemie (International Edition in English), 32, 1208-1208 (1993)
Journal of the Chemical Society. Perkin Transactions 1, 1923-1923 (1992)
Nan Li et al.
Lab on a chip, 8(12), 2105-2112 (2008-11-22)
High-density live cell array serves as a valuable tool for the development of high-throughput immunophenotyping systems and cell-based biosensors. In this paper, we have, for the first time, demonstrated a simple fabrication process to form the hexamethyldisilazane (HMDS) and poly(ethylene...
Haoyu Tang et al.
Biomacromolecules, 11(6), 1585-1592 (2010-05-15)
A series of poly(gamma-chloropropyl-L-glutamate) (PCPLG) with controlled polymer molecular weight (MW = 5-28 kg x mol(-1)) and molecular weight distribution (PDI = 1.16-1.26) have been prepared from hexamethyldisilazane (HMDS)-mediated ring-opening polymerization (ROP) of gamma-chloropropyl-L-glutamic acid based N-carboxylanhydride (CP-NCA). CD, FTIR...

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