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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
235385
tert-Butyl nitrite
90%
Synonym(s):
1,1-Dimethylethyl nitrite
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 25 mL | Available to ship TODAYfromMILWAUKEE | $48.60 | |
| 100 mL | Available to ship TODAYfromMILWAUKEE | $104.00 |
About This Item
Quality Level
assay
90%
refractive index
n20/D 1.368 (lit.)
bp
61-63 °C (lit.)
solubility
alcohol: very soluble(lit.), carbon disulfide: very soluble(lit.), chloroform: very soluble(lit.), diethyl ether: very soluble(lit.), glycerol: insoluble (practically)(lit.), water: slightly soluble(lit.)
density
0.867 g/mL at 25 °C (lit.)
functional group
O-nitroso, nitroso
storage temp.
2-8°C
SMILES string
CC(C)(C)ON=O
InChI
1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
InChI key
IOGXOCVLYRDXLW-UHFFFAOYSA-N
General description
Application
- for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes
- for the preparation of aryl azides from aryl amines[3]
Other Notes
1 of 1
This Item | |||
|---|---|---|---|
| assay 90% | assay ≥90% (GC) | assay 95% | assay ≥99.9% trace metals basis |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
| solubility alcohol: very soluble(lit.), chloroform: very soluble(lit.), glycerol: insoluble (practically)(lit.), carbon disulfide: very soluble(lit.), water: slightly soluble(lit.), diethyl ether: very soluble(lit.) | solubility alcohol: very soluble, chloroform: very soluble, diethyl ether: very soluble, glycerol: insoluble, water: slightly soluble | solubility alcohol: miscible(lit.), diethyl ether: miscible(lit.) | solubility H2O: soluble (highly soluble(lit.)), acetone: soluble ((lit.)), alcohols: soluble ((lit.)) |
| refractive index n20/D 1.368 (lit.) | refractive index n20/D 1.368 | refractive index n20/D 1.376 (lit.) | refractive index - |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - |
| bp 61-63 °C (lit.) | bp 61-63 °C (lit.) | bp 78 °C (lit.) | bp - |
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
14.0 °F - closed cup
flash_point_c
-10 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 235385-25ML | 04061838785046 |
| 235385-100ML | 04061838785039 |
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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