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MilliporeSigma

237442

(R)-(+)-1-(1-Naphthyl)ethylamine

≥99%

Synonym(s):

(R)-(+)-α-Methyl-1-naphthalenemethylamine

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$163.00

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About This Item

Linear Formula:
C10H7CH(CH3)NH2
CAS Number:
Molecular Weight:
171.24
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
223-425-5
Beilstein/REAXYS Number:
2208025
MDL number:
Assay:
≥99%
Form:
liquid

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InChI key

RTCUCQWIICFPOD-SECBINFHSA-N

InChI

1S/C12H13N/c1-9(13)11-8-4-6-10-5-2-3-7-12(10)11/h2-9H,13H2,1H3/t9-/m1/s1

SMILES string

C[C@@H](N)c1cccc2ccccc12

assay

≥99%

form

liquid

optical activity

[α]20/D +55°, c = 2 in ethanol

optical purity

ee: 98% (GLC)

refractive index

n20/D 1.623 (lit.)

bp

153 °C/11 mmHg (lit.)

density

1.067 g/mL at 20 °C (lit.)

functional group

amine

Quality Level

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1 of 4

This Item
23745070942452823
assay

≥99%

assay

≥99%

assay

≥99.0% (sum of enantiomers, GC)

assay

99%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

bp

153 °C/11 mmHg (lit.)

bp

153 °C/11 mmHg (lit.)

bp

-

bp

86 °C/0.05 mmHg (lit.)

refractive index

n20/D 1.623 (lit.)

refractive index

n20/D 1.623 (lit.)

refractive index

-

refractive index

n20/D 1.5523 (lit.)

form

liquid

form

liquid

form

solid

form

-

density

1.067 g/mL at 20 °C (lit.)

density

1.067 g/mL at 20 °C (lit.)

density

-

density

0.985 g/mL at 25 °C (lit.)

Application

Absolute configuration of primary amines determined using chiral (2-nitrophenyl)proline amides and 1H NMR.[1]

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Hee Choon Ahn et al.
Organic letters, 9(19), 3853-3855 (2007-08-23)
N-(2-Nitrophenyl)proline (2-NPP) amides of primary amines have a conformational preference for intramolecular hydrogen bonding. Because of the strong and selective anisotropic effects on the amine substituents, the absolute configuration of alpha-chiral primary amines can be assigned by comparing the 1H

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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