238252

1-Iododecane

98%

• Synonym(s): Decyl iodide
• Linear Formula: CH₃(CH₂)₉I
• CAS Number: 2050-77-3
• Molecular Weight: 268.18
• UNSPSC Code: 12352100
• NACRES: NA.22
• PubChem Substance ID: 24854150
• EC Number: 218-104-1
• Beilstein/REAXYS Number: 1735228
• MDL number: MFCD00001085
• Assay: 98%
• Form: liquid

Properties

• vapor density: >5 (vs air)
• vapor pressure: 0.01 mmHg ( 20 °C)
• assay: 98%
• form: liquid
• contains: copper as stabilizer
• refractive index: n20/D 1.485 (lit.)
• bp: 132 °C/15 mmHg (lit.)
• density: 1.257 g/mL at 25 °C (lit.)
• functional group: alkyl halide, iodo
• SMILES string: CCCCCCCCCCI
• InChI: 1S/C10H21I/c1-2-3-4-5-6-7-8-9-10-11/h2-10H2,1H3
• InChI key: SKIDNYUZJPMKFC-UHFFFAOYSA-N

Description

General description

Electrochemical reduction of 1-iododecane at mercury cathodes in DMF containing tetra-n-butylammonium perchlorate or tetramethyl ammonium perchlorate (supporting electrolyte) has been investigated.

Application

1-Iododecane has been used in the preparation of 9-nonadecanone via palladium-catalyzed carbonylative cross-coupling reaction with 9-octyl-9-borabicyclo[3.3.l]nonane.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk: WGK 3
• flash_point_f: 230.0 °F - closed cup
• flash_point_c: 110 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter