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242861

Sigma-Aldrich

Chloroiodomethane

97%

Linear Formula:
ClCH2I
CAS Number:
Molecular Weight:
176.38
Beilstein:
1730802
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

contains

copper as stabilizer

refractive index

n20/D 1.582 (lit.)

bp

108-109 °C (lit.)

density

2.422 g/mL at 25 °C (lit.)

SMILES string

ClCI

InChI

1S/CH2ClI/c2-1-3/h1H2

InChI key

PJGJQVRXEUVAFT-UHFFFAOYSA-N

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General description

The photolysis of chloroiodomethane in cryogenic matrices along with recombination of the nascent radical pair was studied.

Packaging

5, 25 g in ampule

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Andrew J Sumner et al.
Environmental science & technology, 53(14), 8216-8226 (2019-07-06)
A number of flowback samples derived from horizontally drilled hydraulic fracturing (HDHF) operations reveal consistent detections of halogenated organic species , yet the source of these compounds remains uncertain. Studies simulating subsurface conditions have found that oxidative "breakers" can halogenate certain...
Thomas J Preston et al.
The Journal of chemical physics, 135(11), 114503-114503 (2011-09-29)
Photolysis of chloroiodomethane (CH(2)ClI) in cryogenic matrices followed by recombination of the nascent radical pair produces an isomer (CH(2)Cl-I) that features a halogen-halogen (Cl-I) bond. Using ultrafast laser pulses, it is possible to follow the formation of this isomer by...

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