244988
Bis(1,5-cyclooctadiene)nickel(0)
Synonym(s):
Bis(cyclooctadiene)nickel, Ni(COD)2
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About This Item
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Quality Level
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
parameter
temperature sensitive
mp
60 °C (dec.) (lit.)
storage temp.
−20°C
SMILES string
[Ni].C1CC=CCCC=C1.C2CC=CCCC=C2
InChI
1S/2C8H12.Ni/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H,3-6H2;/b2*2-1-,8-7-;
InChI key
JRTIUDXYIUKIIE-KZUMESAESA-N
1 of 4
This Item | 213934 | 901166 | 237116 |
---|---|---|---|
reaction suitability core: nickel, reagent type: catalyst, reaction type: Cross Couplings | reaction suitability core: nickel, reagent type: catalyst | reaction suitability core: nickel, reaction type: Cross Couplings, reagent type: catalyst | reaction suitability core: nickel, reagent type: catalyst |
Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
storage temp. −20°C | storage temp. 2-8°C | storage temp. - | storage temp. - |
mp 60 °C (dec.) (lit.) | mp 206-209 °C (lit.) | mp >300 °C | mp 250 °C (dec.) (lit.) |
parameter temperature sensitive | parameter - | parameter - | parameter - |
Application
- Oxidative addition reactions
Catalyst for:
- Asymmetric α-arylation and heteroarylation of ketones with chloroarenes
- Cross-coupling reactions
- Regioselective and stereoselective carboxylation/cyclization of allenyl aldehydes under a carbon dioxide atmosphere
- Methyl carboxylation of homopropargylic alcohols
- Stereoselective borylative ketone-diene coupling
- Cycloaddition of benzamides with internal alkynes
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - STOT RE 1
target_organs
Lungs
Storage Class
4.1B - Flammable solid hazardous materials
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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