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245003

Sigma-Aldrich

Dirhenium decacarbonyl

98%

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Synonym(s):
Rhenium carbonyl
Linear Formula:
Re2(CO)10
CAS Number:
Molecular Weight:
652.52
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

assay

98%

form

powder or crystals

reaction suitability

core: rhenium
reagent type: catalyst

mp

170 °C (dec.) (lit.)

SMILES string

[ReH].[ReH].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/10CO.2Re/c10*1-2;;

InChI key

ZIZHEHXAMPQGEK-UHFFFAOYSA-N

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1 of 4

This Item
249742515736299391
vibrant-m

245003

Dirhenium decacarbonyl

vibrant-m

249742

Triosmium dodecacarbonyl

vibrant-m

515736

Rhenium(VII) oxide

vibrant-m

299391

Tetrairidium dodecacarbonyl

form

powder or crystals

form

powder or crystals

form

powder

form

powder

mp

170 °C (dec.) (lit.)

mp

224 °C (lit.)

mp

220 °C (lit.)

mp

195 °C (dec.) (lit.)

reaction suitability

core: rhenium

reaction suitability

core: osmium, reagent type: catalyst

reaction suitability

-

reaction suitability

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

General description

Dirhenium decacarbonyl (Re2(CO)10) is a transition metal carbonyl widely used as a precursor in the chemical vapor deposition (CVD) of metals and the fabrication of composite materials. The endothermic nature of the decomposition of Re2(CO)10 allows for uniform deposition of metallic or alloy coatings on the substrate.

Application

Dirhenium decacarbonyl can be used as a precursor to synthesize:
  • Re nanoparticles via pulsed-laser decomposition.
  • Amide functionalized Re(I) based dinuclear metallacycles that can selectively inhibit certain cancer cells.
  • Twisted ultrathin rhenium disulfide nanoribbons encapsulated in single-walled carbon nanotubes.

Pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Inhalation

Storage Class

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Petros M Sakkas et al.
Ultrasonics sonochemistry, 69, 105250-105250 (2020-07-16)
Rhenium oxide nanoparticles have been prepared using ultrasonication at 20 kHz. Samples characterization was committed via SEM-EDX, TEM, XRD, and Raman spectroscopy. Various experimental parameters were examined, including precursor/substrate amounts, ultrasonication intensity, and type of solvent used. Insights to the agglomeration
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Reliable, controlled doping of 2D transition metal dichalcogenides will enable the realization of next-generation electronic, logic-memory, and magnetic devices based on these materials. However, to date, accurate control over dopant concentration and scalability of the process remains a challenge. Here

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