247057

Sigma-Aldrich

Tetrabutylammonium (meta)periodate

Linear Formula:
(CH3CH2CH2CH2)4N(IO4)
CAS Number:
Molecular Weight:
433.37
Beilstein/REAXYS Number:
4621593
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

assay

29.3% iodine (I) basis (titration)

Quality Level

form

solid

reaction suitability

reagent type: oxidant

mp

175 °C (dec.) (lit.)

SMILES string

[O-]I(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.HIO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1

InChI key

PYVXLMQALOZKES-UHFFFAOYSA-M

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Application

Tetrabutylammonium (meta)periodate (DCM) can be oxidated for the synthesis of aryl nitroso derivatives. It can also be used in the formation of an ionic liquid for the synthesis of aromatic carboxylic acids.

Packaging

25 g in glass bottle

Pictograms

Flame over circleExclamation mark

Signal Word

Danger

Hazard Statements

Precautionary Statements

Target Organs

Respiratory system

RIDADR

UN 1479 5.1 / PGII

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

Efficient synthesis of aromatic carboxylic acids from aryl ketones in ionic liquid
Lee JC and Lee J
Synthetic Communications, 36(8), 1071-1074 (2006)
Carmen E Castillo et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(15), 4946-4954 (2020-12-23)
Oxoiron(IV) complexes bearing tetradentate ligands have been extensively studied as models for the active oxidants in non-heme iron-dependent enzymes. These species are commonly generated by oxidation of their ferrous precursors. The mechanisms of these reactions have seldom been investigated. In...
Study of Enantioselective Catalysis of Nitroso-Diels-Alder Reaction on Solid Support
Kratka L and Hlavavc J
ChemistrySelect, 2(14), 3987-3992 (2017)
Michelle L Ingalsbe et al.
Bioorganic & medicinal chemistry letters, 19(17), 4984-4987 (2009-08-08)
Due to the increasing number of strains of drug-resistant bacteria, the development of new antibiotics has become increasingly important. The antibacterial properties of quaternary amines and their derivatives on both Gram-positive and Gram-negative bacteria are well known. However, an encompassing...

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