248533

Sigma-Aldrich

5-Norbornene-2-methanol

98%, mixture of endo and exo

Empirical Formula (Hill Notation):
C8H12O
CAS Number:
Molecular Weight:
124.18
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

98%

refractive index

n20/D 1.500 (lit.)

bp

97 °C/20 mmHg (lit.)

density

1.027 g/mL at 25 °C (lit.)

SMILES string

OCC1CC@@H2CC@H1C=C2

InChI

1S/C8H12O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-9H,3-5H2/t6-,7+,8?/m0/s1

InChI key

LUMNWCHHXDUKFI-KJFJCRTCSA-N

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General description

Co-polymerization of 5-norbornene-2-methanol with ethylene using heterogeneous silica supported catalysts has been reported.

Application

5-Norbornene-2-methanol has been used in the preparation of:
  • 4-(norborn-2-ene-5-ylmethyleneoxy)-2,2′:6′,2′′-terpyridine
  • 5- {(3,5-di-t-butyl-4-hydroxy-benzoyl)oxymethyl}-2-norbornene (BHBN)

Packaging

5 g in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

Xn

Risk Statement

20/21/22

Safety Statement

36/37/39-45

WGK Germany

WGK 3

Flash Point(F)

188.6 °F - closed cup

Flash Point(C)

87 °C - closed cup

Access to heterogeneous atom-transfer radical polymerization (ATRP) catalysts based on dipyridylamine and terpyridine via ring-opening metathesis polymerization (ROMP).
Kroll R, et al.
Macromolecular Chemistry and Physics, 202(5), 645-653 (2001)
Synthesis of a polynorbornene containing 3, 5-di-TERT-butyl-4-hydroxybenzoyl group.
Tienkopatchev MA, et al.
Polymer Bull., 34(4), 385-391 (1995)
Zhen Zhang et al.
Polymers, 12(4) (2020-04-16)
Injectable, covalently cross-linked hydrogels have been widely investigated in drug delivery systems due to their superior mechanical properties and long-term stability. Conventional covalently cross-linked hydrogels are formed by chemical reactions that may interfere with natural biochemical processes. In this work...
Homogeneous and heterogeneous metallocene/MAO-catalyzed polymerization of functionalized olefins.
Goretzki R and Fink G.
Macromolecular Chemistry and Physics, 200(4), 881-886 (1999)

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