249955

Sigma-Aldrich

Tin(IV) chloride solution

1.0 M in methylene chloride

Synonym(s):
Stannic chloride, Tin tetrachloride
Linear Formula:
SnCl4
CAS Number:
Molecular Weight:
260.52
MDL number:
PubChem Substance ID:
Pricing and availability is not currently available.

Quality Level

reaction suitability

core: tin
reagent type: catalyst

concentration

1.0 M in methylene chloride

density

1.419 g/mL at 25 °C

SMILES string

ClSn(Cl)(Cl)Cl

InChI

1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4

InChI key

HPGGPRDJHPYFRM-UHFFFAOYSA-J

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General description

Tin(IV) chloride shows Lewis acid character and is generally used for the synthesis of SnO2 nanoparticles by sol-gel method.

Application

Tin(IV) chloride solution can be used for chloromethylation reaction of polysulfones to develop polymer electrolyte membranes.

Packaging

4×25, 100, 800 mL in Sure/Seal™
The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

C

Risk Statement

34-37-40-52/53-67

Safety Statement

26-36/37/39-45-61

RIDADR

UN 3264 8 / PGII

WGK Germany

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Solid-State and Solution Structural Study of Acetylacetone-Modified Tin (IV) Chloride Used as a Precursor of SnO2 Nanoparticles Prepared by a Sol- Gel Route.
Briois V, et al.
Chemistry of Materials, 16(20), 3885-3894 (2004)
Phosphoric acid doped polysulfone membranes with aminopyridine pendant groups and imidazole cross-links.
Hink S, et al.
European Polymer Journal, 72(20), 102-113 (2015)
Molecular addition compounds of tin (IV) chloride. I. Interaction with benzonitriles in benzene solution.
Brown TL and Kubota M
Journal of the American Chemical Society, 83(2), 331-334 (1961)
Yu-Jun Zhao et al.
Chemical communications (Cambridge, England), (12)(12), 1434-1436 (2008-03-14)
This communication describes a highly efficient intermolecular polyene cyclization method using steroidal acetals as the initiators to synthesize tetracyclic terpenoids; both good yields and good asymmetric induction were obtained.
Jia Lu Xue et al.
Carbohydrate research, 344(13), 1646-1653 (2009-07-15)
Glycosidation of sugar peracetates (D-gluco, D-galacto) with SnCl(4) and CF(3)CO(2)Ag led to either 1,2-cis-, or 1,2-trans-glycosides, depending primarily on the alcohols used. In particular, 1,2-trans-glycosides, expected from acyl-protected glycosyl donors, were formed in high yields with alcohols sharing specific features...

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