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Chlorotriisopropoxytitanium(IV)

Name: Chlorotriisopropoxytitanium(IV)
Brand: ALDRICH
Price: 180 USD
Availability: InStock

95%

Synonym(s):

Chlorotitanium(IV) triisopropoxide, Titanium(IV) chloride triisopropoxide

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Pack Size	SKU	Availability	Price
100 g		Available to ship TODAYfromMILWAUKEE	$180.00

About This Item

Linear Formula:

[(CH₃)₂CHO]₃TiCl

CAS Number:

20717-86-6

Molecular Weight:

260.58

UNSPSC Code:

12352103

NACRES:

NA.23

PubChem Substance ID:

24855066

MDL number:

MFCD00009861

Beilstein/REAXYS Number:

4163222

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Properties

Quality Level

100

assay

95%

form

liquid

reaction suitability

core: titanium, reagent type: catalyst

mp

35-40 °C

density

1.091 g/mL at 25 °C (lit.)

SMILES string

CC(C)O[Ti](Cl)(OC(C)C)OC(C)C

InChI

1S/3C3H7O.ClH.Ti/c3*1-3(2)4;;/h3*3H,1-2H3;1H;/q3*-1;;+4/p-1

InChI key

IFMWVBVPVXRZHE-UHFFFAOYSA-M

Description

Application

Useful additive for increased regio- and stereocontrol in aldol reactions.

Other Notes

Storage below 25 °C may cause crystallization. Moving container to a warm location should remelt the solid (mp ~35 °C). Recrystallization occurs slowly. Thus, the liquid may be transferred using syringe techniques.

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1 of 1

This Item	252670	494143	697079
Sigma-Aldrich 250627 Chlorotriisopropoxytitanium(IV)	Sigma-Aldrich 252670 Chlorotriisopropoxytitanium(IV) solution	Sigma-Aldrich 494143 Titanium(IV) diisopropoxidebis(2,2,6,6-tetramethyl-3,5-heptanedionate)	Sigma-Aldrich 697079 Titanium tetrachloride
form liquid	form solution	form solid	form liquid
assay 95%	assay -	assay 99.99%	assay ≥99.995% (trace metals analysis)
mp 35-40 °C	mp -	mp 171.1-184.6 °C (lit.)	mp −25 °C (lit.)
density 1.091 g/mL at 25 °C (lit.)	density 0.775 g/mL at 25 °C	density -	density 1.73 g/mL at 20 °C (lit.)
reaction suitability core: titanium, reagent type: catalyst	reaction suitability core: titanium, reagent type: catalyst	reaction suitability core: titanium, reagent type: catalyst	reaction suitability core: titanium, reagent type: catalyst
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 100

pictograms

GHS02,GHS05

signalword

Danger

hcodes

H228,H314

pcodes

P210 - P240 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

71.6 °F - closed cup

flash_point_c

22 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number

0000445201

0000410684

0000249756

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Global Trade Item Number

SKU	GTIN
250627-800G	04061838145543
250627-100G	04061838138590

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