255718

Cesium fluoride

99.99% trace metals basis

• Synonym(s): NSC 84270
• Empirical Formula (Hill Notation): CsF
• CAS Number: 13400-13-0
• Molecular Weight: 151.90
• EC Number: 236-487-3
• MDL number: MFCD00010960
• PubChem Substance ID: 24855475
• NACRES: NA.23

Properties

• Quality Level: 100
• assay: 99.99% trace metals basis
• form: solid
• impurities: ≤150.0 ppm Trace Metal Analysis
• mp: 682 °C (lit.)
• solubility: methanol: slightly soluble(lit.); pyridine: insoluble(lit.)
• density: 4.115 g/mL at 25 °C (lit.)
• SMILES string: [F-].[Cs+]
• InChI: 1S/Cs.FH/h;1H/q+1;/p-1
• InChI key: XJHCXCQVJFPJIK-UHFFFAOYSA-M

Description

Application

Reactant for:

• Preparation of building blocks for synthesis of fluoroallylic compounds
• Synthesis of alcohols via hydrolysis of alkyl silyl ethers at neutral pH in buffered mixed organic-aqueous solutions
• Nucleophilic fluorination of alkynyliodonium salts to form fluorovinylic compounds
• Nucleophilic aromatic substitution (SNAr) reactions

Used in the successful synthesis of a single-crystal Dion-Jacobson phase, CsLaTa₂O₇, that has applications in photocatalysis and superconductivity.

Used as a base in the Suzuki carbonylative coupling of enol triflates with vinyl boronic acids.

Packaging

10, 50 g in poly bottle

Safety Information

• Pictograms: GHS05,GHS07,GHS08
• Signal Word: Danger
• Hazard Statements: H302 - H318 - H361d - H373 - H412
• Precautionary Statements: P202 - P273 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - STOT RE 2
• Supplementary Hazards: EUH032
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 2
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves