256447

Sigma-Aldrich

Bis(cyclopentadienyl)molybdenum(IV) dichloride

95%

Empirical Formula (Hill Notation):
C10H10Cl2Mo
CAS Number:
Molecular Weight:
297.03
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

95%

form

crystalline powder
powder, crystals or chunks

reaction suitability

core: molybdenum
reagent type: catalyst

SMILES string

Cl[Mo]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.2ClH.Mo/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

YQZUTDPJTAZPQJ-UHFFFAOYSA-L

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

P Manohari Abeysinghe et al.
Dalton transactions (Cambridge, England : 2003), (32)(32), 3474-3482 (2007-08-08)
This Perspective will focus on recent developments in the field of antitumour metallocenes structurally related to titanocene dichloride. Despite extensive testing of titanocene dichloride which culminated in phase I and II clinical trials, further trials have been abandoned. While DNA...
Jenny B Waern et al.
Journal of medicinal chemistry, 48(6), 2093-2099 (2005-03-18)
The effect of aqueous solubility, charge, and lability of four thiol derivatives of the antitumor metallocene molybdocene dichloride (Cp(2)MoCl(2)) on the cell uptake and cytotoxicity against V79 Chinese hamster lung cells has been determined. Addition of 4-thiol-2,3,5,6-tetrafluorobenzoic acid, 1-thio-beta-d-glucose, and...
Jenny B Waern et al.
Inorganic chemistry, 43(1), 206-213 (2004-01-06)
The relative affinity of molybdocene dichloride (Cp(2)MoCl(2)) for the thiol, amino, carboxylate, phosphate(O) and heterocyclic(N) donor ligands present in amino acids and nucleotides, has been studied in aqueous solutions at pH 2-7, using (1)H, (13)C and (31)P NMR spectroscopy. Molybdocene...
E Tonew et al.
Zentralblatt fur Bakteriologie, Mikrobiologie und Hygiene. 1. Abt. Originale A, Medizinische Mikrobiologie, Infektionskrankheiten und Parasitologie = International journal of microbiology and hygiene. A, Medical microbiology, infectious..., 250(4), 425-430 (1981-11-01)
In view of the fact that bis cyclopentadienyl metal dihalides are known to be anti-tumour drugs, we have investigated the antiviral activity of this type of coordination compounds. Bis cyclopentadienyl titanium dichloride (a) has shown significant antiviral efficiency in vitro...
Louis Y Kuo et al.
Inorganic chemistry, 44(15), 5537-5541 (2005-07-19)
Thiophosphinate hydrolysis involving P-S bond scission is desirable for the degradation of organophosphate neurotoxins, and we report the first case for such a hydrolytic process by an organometallic compound. The metallocene, bis(cyclopentadienyl)molybdenum(IV) dichloride, Cp(2)MoCl(2) (Cp = eta(5)-C(5)H(5)), hydrolyzes a variety...

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