259039

Sigma-Aldrich

Chloro(1,5-hexadiene)rhodium(I),dimer

98%

Synonym(s):
Di-μ-chlorobis[(1,2,5,6-η)-1,5-hexadiene]dirhodium
Linear Formula:
[(H2C=CHCH2CH2CH=CH2)RhCl]2
CAS Number:
Molecular Weight:
434.96
MDL number:
PubChem Substance ID:
NACRES:
NA.22

assay

98%

reaction suitability

core: rhodium
reagent type: catalyst

mp

118-120 °C (lit.)

SMILES string

Cl[Rh].Cl[Rh].C=CCCC=C.C=CCCC=C

InChI

1S/2C6H10.2ClH.2Rh/c2*1-3-5-6-4-2;;;;/h2*3-4H,1-2,5-6H2;2*1H;;/q;;;;2*+1/p-2

InChI key

HXNWPVBAYNUADR-UHFFFAOYSA-L

Application

Catalyst for:
  • Hydrogenation
  • Enantioselective hydrosilylation
Useful catalyst for the reduction of arenes and heterocyclic compounds using CTAB or THS as phase-transfer catalyst.

Packaging

250 mg in glass bottle

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Precautionary Statements

Target Organs

Respiratory system

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Aldrichimica Acta, 18, 111-111 (1985)
Organometallics, 2, 1055-1055 (1983)

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