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259039

Sigma-Aldrich

Chloro(1,5-hexadiene)rhodium(I),dimer

98%

Synonym(s):
Di-μ-chlorobis[(1,2,5,6-η)-1,5-hexadiene]dirhodium
Linear Formula:
[(H2C=CHCH2CH2CH=CH2)RhCl]2
CAS Number:
Molecular Weight:
434.96
MDL number:
PubChem Substance ID:
NACRES:
NA.22

assay

98%

reaction suitability

core: rhodium
reagent type: catalyst

mp

118-120 °C (lit.)

SMILES string

Cl[Rh].Cl[Rh].C=CCCC=C.C=CCCC=C

InChI

1S/2C6H10.2ClH.2Rh/c2*1-3-5-6-4-2;;;;/h2*3-4H,1-2,5-6H2;2*1H;;/q;;;;2*+1/p-2

InChI key

HXNWPVBAYNUADR-UHFFFAOYSA-L

Application

Catalyst for:
  • Hydrogenation
  • Enantioselective hydrosilylation
Useful catalyst for the reduction of arenes and heterocyclic compounds using CTAB or THS as phase-transfer catalyst.

Packaging

250 mg in glass bottle

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(C)

Not applicable

Certificate of Analysis

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Certificate of Origin

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